Encapsulation of single-molecule magnets in carbon nanotubes

Next-generation electronic, photonic or spintronic devices will be based on nanoscale functional units, such as quantum dots, isolated spin centres or single-molecule magnets. The key challenge is the coupling of the nanoscale units to the macroscopic world, which is essential for read and write pur...

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Autores: Giménez López, María del Carmen, Moro, Fabrizio, La Torre, Alessandro, Gómez-García, Carlos J., Brown, Paul D., van Slageren, Joris, Khlobystov, Andrei N.
Tipo de recurso: artículo
Fecha de publicación:2011
País:España
Institución:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/32238
Acceso en línea:http://hdl.handle.net/10347/32238
Access Level:acceso abierto
Palabra clave:2303 Química inorgánica
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spelling Encapsulation of single-molecule magnets in carbon nanotubesGiménez López, María del CarmenMoro, FabrizioLa Torre, AlessandroGómez-García, Carlos J.Brown, Paul D.van Slageren, JorisKhlobystov, Andrei N.2303 Química inorgánicaNext-generation electronic, photonic or spintronic devices will be based on nanoscale functional units, such as quantum dots, isolated spin centres or single-molecule magnets. The key challenge is the coupling of the nanoscale units to the macroscopic world, which is essential for read and write purposes. Carbon nanotubes with one macroscopic and two nanoscopic dimensions provide an excellent means to achieve this coupling. Although the dimensions of nanotube internal cavities are suitable for hosting a wide range of different molecules, to our knowledge, no examples of molecular magnets inserted in nanotubes have been reported to date. Here we report the successful encapsulation of single-molecule magnets in carbon nanotubes, yielding a new type of hybrid nanostructure that combines all the key single-molecule magnet properties of the guest molecules with the functional properties of the host nanotube. The findings may pave the way to the construction of spintronic or ultrahigh-density magnetic data storage devices.Nature ResearchUniversidade de Santiago de Compostela. Departamento de Química Inorgánica20112011-01-0120112011-01-01journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10347/32238reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/322382026-06-15T12:47:27Z
dc.title.none.fl_str_mv Encapsulation of single-molecule magnets in carbon nanotubes
title Encapsulation of single-molecule magnets in carbon nanotubes
spellingShingle Encapsulation of single-molecule magnets in carbon nanotubes
Giménez López, María del Carmen
2303 Química inorgánica
title_short Encapsulation of single-molecule magnets in carbon nanotubes
title_full Encapsulation of single-molecule magnets in carbon nanotubes
title_fullStr Encapsulation of single-molecule magnets in carbon nanotubes
title_full_unstemmed Encapsulation of single-molecule magnets in carbon nanotubes
title_sort Encapsulation of single-molecule magnets in carbon nanotubes
dc.creator.none.fl_str_mv Giménez López, María del Carmen
Moro, Fabrizio
La Torre, Alessandro
Gómez-García, Carlos J.
Brown, Paul D.
van Slageren, Joris
Khlobystov, Andrei N.
author Giménez López, María del Carmen
author_facet Giménez López, María del Carmen
Moro, Fabrizio
La Torre, Alessandro
Gómez-García, Carlos J.
Brown, Paul D.
van Slageren, Joris
Khlobystov, Andrei N.
author_role author
author2 Moro, Fabrizio
La Torre, Alessandro
Gómez-García, Carlos J.
Brown, Paul D.
van Slageren, Joris
Khlobystov, Andrei N.
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade de Santiago de Compostela. Departamento de Química Inorgánica

dc.subject.none.fl_str_mv 2303 Química inorgánica
topic 2303 Química inorgánica
description Next-generation electronic, photonic or spintronic devices will be based on nanoscale functional units, such as quantum dots, isolated spin centres or single-molecule magnets. The key challenge is the coupling of the nanoscale units to the macroscopic world, which is essential for read and write purposes. Carbon nanotubes with one macroscopic and two nanoscopic dimensions provide an excellent means to achieve this coupling. Although the dimensions of nanotube internal cavities are suitable for hosting a wide range of different molecules, to our knowledge, no examples of molecular magnets inserted in nanotubes have been reported to date. Here we report the successful encapsulation of single-molecule magnets in carbon nanotubes, yielding a new type of hybrid nanostructure that combines all the key single-molecule magnet properties of the guest molecules with the functional properties of the host nanotube. The findings may pave the way to the construction of spintronic or ultrahigh-density magnetic data storage devices.
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-01-01
2011
2011-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10347/32238
url http://hdl.handle.net/10347/32238
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Nature Research
publisher.none.fl_str_mv Nature Research
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
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