Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks

[EN] Large scale production of green CH3OH obtained from CO2 and green H-2 is a highly wanted process due to the role of CH3OH as H-2/energy carrier and for producing chemicals. Starting with a short summary of the advantages of metal-organic frameworks (MOFs) as catalysts in liquid-phase reactions,...

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Autores: Dhakshinamoorthy, Amarajothi, Navalón Oltra, Sergio|||0000-0001-8423-0759, Primo Arnau, Ana Maria|||0000-0001-9205-2278, García Gómez, Hermenegildo|||0000-0002-9664-493X
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/204761
Acceso en línea:https://riunet.upv.es/handle/10251/204761
Access Level:acceso abierto
Palabra clave:CO2 Hydrogenation
Gas-Phase Catalysis
Heterogeneous Catalysis
Metal-Organic Frameworks
Methanol Synthesis
QUIMICA ORGANICA
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oai_identifier_str oai:riunet.upv.es:10251/204761
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
title Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
spellingShingle Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
Dhakshinamoorthy, Amarajothi
CO2 Hydrogenation
Gas-Phase Catalysis
Heterogeneous Catalysis
Metal-Organic Frameworks
Methanol Synthesis
QUIMICA ORGANICA
title_short Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
title_full Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
title_fullStr Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
title_full_unstemmed Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
title_sort Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic Frameworks
dc.creator.none.fl_str_mv Dhakshinamoorthy, Amarajothi
Navalón Oltra, Sergio|||0000-0001-8423-0759
Primo Arnau, Ana Maria|||0000-0001-9205-2278
García Gómez, Hermenegildo|||0000-0002-9664-493X
author Dhakshinamoorthy, Amarajothi
author_facet Dhakshinamoorthy, Amarajothi
Navalón Oltra, Sergio|||0000-0001-8423-0759
Primo Arnau, Ana Maria|||0000-0001-9205-2278
García Gómez, Hermenegildo|||0000-0002-9664-493X
author_role author
author2 Navalón Oltra, Sergio|||0000-0001-8423-0759
Primo Arnau, Ana Maria|||0000-0001-9205-2278
García Gómez, Hermenegildo|||0000-0002-9664-493X
author2_role author
author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Grupo de Fotoquímica Heterogénea y Medioambiental
European Commission
GENERALITAT VALENCIANA
Agencia Estatal de Investigación
European Regional Development Fund
Ministerio de Ciencia e Innovación
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv CO2 Hydrogenation
Gas-Phase Catalysis
Heterogeneous Catalysis
Metal-Organic Frameworks
Methanol Synthesis
QUIMICA ORGANICA
topic CO2 Hydrogenation
Gas-Phase Catalysis
Heterogeneous Catalysis
Metal-Organic Frameworks
Methanol Synthesis
QUIMICA ORGANICA
description [EN] Large scale production of green CH3OH obtained from CO2 and green H-2 is a highly wanted process due to the role of CH3OH as H-2/energy carrier and for producing chemicals. Starting with a short summary of the advantages of metal-organic frameworks (MOFs) as catalysts in liquid-phase reactions, the present article highlights the opportunities that MOFs may offer also for some gas-phase reactions, particularly for the selective CO2 hydrogenation to CH3OH. It is commented that there is a temperature compatibility window that combines the thermal stability of some MOFs with the temperature required in the CO2 hydrogenation to CH3OH that frequently ranges from 250 to 300 degrees C. The existing literature in this area is briefly organized according to the role of MOF as providing the active sites or as support of active metal nanoparticles (NPs). Emphasis is made to show how the flexibility in design and synthesis of MOFs can be used to enhance the catalytic activity by adjusting the composition of the nodes and the structure of the linkers. The influence of structural defects and material crystallinity, as well as the role that should play theoretical calculations in models have also been highlighted.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-01-15
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/204761
url https://riunet.upv.es/handle/10251/204761
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-123856OB-I00 FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS
European Commission https://doi.org/10.13039/501100000780 H2020 101022649 International cooperation for selective conversion of CO2 into METHAnol under SOLar light
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 PID2021-126071OB-C21 APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCIÓN DE COMBUSTIBLES SOLARES
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038 HETEROGENEOUS (ELECTRO-
Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023 ELECTRODOS Y FOTOCATALIZADORES A BASE DE GRAFENO
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX-2021-001230-S
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Selective Gas-Phase Hydrogenation of CO2 to Methanol Catalysed by Metal-Organic FrameworksDhakshinamoorthy, AmarajothiNavalón Oltra, Sergio|||0000-0001-8423-0759Primo Arnau, Ana Maria|||0000-0001-9205-2278García Gómez, Hermenegildo|||0000-0002-9664-493XCO2 HydrogenationGas-Phase CatalysisHeterogeneous CatalysisMetal-Organic FrameworksMethanol SynthesisQUIMICA ORGANICA[EN] Large scale production of green CH3OH obtained from CO2 and green H-2 is a highly wanted process due to the role of CH3OH as H-2/energy carrier and for producing chemicals. Starting with a short summary of the advantages of metal-organic frameworks (MOFs) as catalysts in liquid-phase reactions, the present article highlights the opportunities that MOFs may offer also for some gas-phase reactions, particularly for the selective CO2 hydrogenation to CH3OH. It is commented that there is a temperature compatibility window that combines the thermal stability of some MOFs with the temperature required in the CO2 hydrogenation to CH3OH that frequently ranges from 250 to 300 degrees C. The existing literature in this area is briefly organized according to the role of MOF as providing the active sites or as support of active metal nanoparticles (NPs). Emphasis is made to show how the flexibility in design and synthesis of MOFs can be used to enhance the catalytic activity by adjusting the composition of the nodes and the structure of the linkers. The influence of structural defects and material crystallinity, as well as the role that should play theoretical calculations in models have also been highlighted.Financial support by the Spanish Ministry of Science and Innovation (CEX-2021-001230-S and PDI2021-0126071-OB-CO21 funded by MCIN/AEI/ 10.13039/501100011033) and Generalitat Valenciana (Prometeo 2021/038 and Advanced Materials programme Graphica MFA/2022/023 with funding from European Union NextGenerationEU PRTR-C17.I1). AD is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU). S.N. thanks the support of Grant PID2021-123856OBI00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe. The METHASOL project receives funding from the European Union Horizon 2020 research and innovation programme under Grant Agreement No 101022649.John Wiley & SonsInstituto Universitario Mixto de Tecnología QuímicaDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialGrupo de Fotoquímica Heterogénea y MedioambientalEuropean CommissionGENERALITAT VALENCIANAAgencia Estatal de InvestigaciónEuropean Regional Development FundMinisterio de Ciencia e InnovaciónUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-01-15journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/204761reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-123856OB-I00 FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOSEuropean Commission https://doi.org/10.13039/501100000780 H2020 101022649 International cooperation for selective conversion of CO2 into METHAnol under SOLar lightAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 PID2021-126071OB-C21 APLICANDO MXENOS COMO CATALIZADORES DEFINITIVOS PARA LA PRODUCCIÓN DE COMBUSTIBLES SOLARESGeneralitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038 HETEROGENEOUS (ELECTRO-Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023 ELECTRODOS Y FOTOCATALIZADORES A BASE DE GRAFENOAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX-2021-001230-Sopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2047612026-06-13T07:49:27Z
score 15,301603

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