Excess properties of mixtures containing 2-(2-ethoxyethoxy)ethanol, methylcyclohexane, cyclohexane and 1‑hexene as fuel representative

The experimental and modelling excess enthalpy, HE, data for the following binary and ternary mixtures: methylcyclohexane (1) + 1‑hexene (2), 2-(2-ethoxyethoxy)ethanol (1) + 1‑hexene (2) + cyclohexane (3), and 2-(2-ethoxyethoxy)ethanol (1) + methylcyclohexane (2) + 1‑hexene (3) are studied in this w...

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Detalles Bibliográficos
Autores: Lifi, Mohamed, Rubio Pérez, Gabriel, Lifi, Houda, Muñoz Rujas, Natalia, Aguilar Romero, Fernando, Alaoui, Fatima E. M.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2022
País:España
Institución:Universidad de Burgos (UBU)
Repositorio:Repositorio Institucional de la Universidad de Burgos (RIUBU)
OAI Identifier:oai:riubu.ubu.es:10259/11431
Acceso en línea:https://hdl.handle.net/10259/11431
Access Level:acceso abierto
Palabra clave:Excess enthalpy
Oxygenated compound
Diesel fuel
Termodinámica
Ingeniería Química
Thermodynamics
Chemical engineering
Descripción
Sumario:The experimental and modelling excess enthalpy, HE, data for the following binary and ternary mixtures: methylcyclohexane (1) + 1‑hexene (2), 2-(2-ethoxyethoxy)ethanol (1) + 1‑hexene (2) + cyclohexane (3), and 2-(2-ethoxyethoxy)ethanol (1) + methylcyclohexane (2) + 1‑hexene (3) are studied in this work at two different temperatures (298.15 and 313.15) K and 0.1 MPa. To measure the HE of the studied binary and ternary mixtures, a quasi-isothermal flow calorimeter was used. All the binary and ternary mixtures present an endothermic behavior at the chosen temperatures. Measured data of HE were correlated using modified Redlich-Kister equation, NRTL and UNIQUAC models.