Parametrization of Catalytic Organic Reactions with Convex Hammett Plots
[EN] Quantification is essential to fairly compare between synthetic reactions in chemistry. Here we propose two new parameters called "adapted sensitivity constant" (rho(adap)) and "substrate electronics adaptability" (SEA), easily obtainable from Hammett plots,...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | inglés |
| OAI Identifier: | oai:riunet.upv.es:10251/204523 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/204523 |
| Access Level: | acceso abierto |
| Palabra clave: | Hammett plot,catalysis Parametrization Organic synthesis Substrate scope Metal clusters Semi-hydrogenation of alkynes Styrene coupling |
| Sumario: | [EN] Quantification is essential to fairly compare between synthetic reactions in chemistry. Here we propose two new parameters called "adapted sensitivity constant" (rho(adap)) and "substrate electronics adaptability" (SEA), easily obtainable from Hammett plots, to assess the ability of a (catalytic) reaction to transform substrates with opposing electronics. These new parameters allow one to list reactions, catalyzed or not, as a function of substrate scope. |
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