Towards the tailored design of benzotriazinyl-based organic radicals displaying a spin transition

The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl- 1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of...

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Detalhes bibliográficos
Autores: Fumanal Quintana, María, Vela Llausí, Sergi, Novoa Vide, Juan J., Ribas Ariño, Jordi
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2015
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/206388
Acesso em linha:https://hdl.handle.net/2445/206388
Access Level:Acceso aberto
Palavra-chave:Ferromagnetisme
Propietats magnètiques
Ferromagnetism
Magnetic properties
Descrição
Resumo:The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl- 1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of radicals, and how those can be exploited by a rational design of the spin-carrying units.