Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer

Modification of the polymer-polymer interfacial tension is a way to tailor-make particle morphology of waterborne polymer-polymer hybrids. This allows achieving a broader spectrum of application properties and maximizing the synergy of the positive properties of both polymers, avoiding their drawbac...

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Detalles Bibliográficos
Autores: Akhmatskaya, E., Asua, J.M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2012
País:España
Institución:Basque Center for Applied Mathematics (BCAM)
Repositorio:BIRD. BCAM's Institutional Repository Data
OAI Identifier:oai:bird.bcamath.org:20.500.11824/423
Acceso en línea:http://hdl.handle.net/20.500.11824/423
Access Level:acceso abierto
Palabra clave:development of particle morphology
dynamic modeling
emulsion polymerization
graft copolymers
grafting
miniemulsion polymerization
morphology
polymer-polymer hybrid
seeded emulsion polymerization
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spelling Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymerAkhmatskaya, E.Asua, J.M.development of particle morphologydynamic modelingemulsion polymerizationgraft copolymersgraftingminiemulsion polymerizationmorphologypolymer-polymer hybridseeded emulsion polymerizationModification of the polymer-polymer interfacial tension is a way to tailor-make particle morphology of waterborne polymer-polymer hybrids. This allows achieving a broader spectrum of application properties and maximizing the synergy of the positive properties of both polymers, avoiding their drawbacks. In situ formation of graft copolymer during polymerization is an efficient way to modify the polymer-polymer interfacial tension. Currently, no dynamic model is available for polymer-polymer hybrids in which a graft copolymer is generated during polymerization. In this article, a novel model based on stochastic dynamics is developed for predicting the dynamics of the development of particle morphology for composite waterborne systems in which a graft copolymer is produced in situ during the process.201720172012info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/20.500.11824/423reponame:BIRD. BCAM's Institutional Repository Datainstname:Basque Center for Applied Mathematics (BCAM)Ingléshttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84857303327&doi=10.1002%2fpola.25904&partnerID=40&md5=29f4c6153a77790ab6d534495858de6aReconocimiento-NoComercial-CompartirIgual 3.0 Españahttp://creativecommons.org/licenses/by-nc-sa/3.0/es/info:eu-repo/semantics/openAccessoai:bird.bcamath.org:20.500.11824/4232026-06-19T12:47:47Z
dc.title.none.fl_str_mv Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
title Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
spellingShingle Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
Akhmatskaya, E.
development of particle morphology
dynamic modeling
emulsion polymerization
graft copolymers
grafting
miniemulsion polymerization
morphology
polymer-polymer hybrid
seeded emulsion polymerization
title_short Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
title_full Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
title_fullStr Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
title_full_unstemmed Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
title_sort Dynamic modeling of the morphology of latex particles with in situ formation of graft copolymer
dc.creator.none.fl_str_mv Akhmatskaya, E.
Asua, J.M.
author Akhmatskaya, E.
author_facet Akhmatskaya, E.
Asua, J.M.
author_role author
author2 Asua, J.M.
author2_role author
dc.subject.none.fl_str_mv development of particle morphology
dynamic modeling
emulsion polymerization
graft copolymers
grafting
miniemulsion polymerization
morphology
polymer-polymer hybrid
seeded emulsion polymerization
topic development of particle morphology
dynamic modeling
emulsion polymerization
graft copolymers
grafting
miniemulsion polymerization
morphology
polymer-polymer hybrid
seeded emulsion polymerization
description Modification of the polymer-polymer interfacial tension is a way to tailor-make particle morphology of waterborne polymer-polymer hybrids. This allows achieving a broader spectrum of application properties and maximizing the synergy of the positive properties of both polymers, avoiding their drawbacks. In situ formation of graft copolymer during polymerization is an efficient way to modify the polymer-polymer interfacial tension. Currently, no dynamic model is available for polymer-polymer hybrids in which a graft copolymer is generated during polymerization. In this article, a novel model based on stochastic dynamics is developed for predicting the dynamics of the development of particle morphology for composite waterborne systems in which a graft copolymer is produced in situ during the process.
publishDate 2012
dc.date.none.fl_str_mv 2012
2017
2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.11824/423
url http://hdl.handle.net/20.500.11824/423
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://www.scopus.com/inward/record.uri?eid=2-s2.0-84857303327&doi=10.1002%2fpola.25904&partnerID=40&md5=29f4c6153a77790ab6d534495858de6a
dc.rights.none.fl_str_mv Reconocimiento-NoComercial-CompartirIgual 3.0 España
http://creativecommons.org/licenses/by-nc-sa/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Reconocimiento-NoComercial-CompartirIgual 3.0 España
http://creativecommons.org/licenses/by-nc-sa/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:BIRD. BCAM's Institutional Repository Data
instname:Basque Center for Applied Mathematics (BCAM)
instname_str Basque Center for Applied Mathematics (BCAM)
reponame_str BIRD. BCAM's Institutional Repository Data
collection BIRD. BCAM's Institutional Repository Data
repository.name.fl_str_mv
repository.mail.fl_str_mv
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