The reciprocal SN2 and SE2 reactions of ammonia borane
The reactions here explored are microscopic analogs of Newton cradle: left thing attack, right thing leaves and central thing remains unaffected. We have studied symmetric S2 reactions, X = N or E, where the attacking and leaving molecules are the same: HN, HB, HC and the central molecules are HB (S...
| Authors: | , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2022 |
| Country: | España |
| Institution: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repository: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/285443 |
| Online Access: | http://hdl.handle.net/10261/285443 |
| Access Level: | Open access |
| Keyword: | SN2 SE2 Ammonia borane Ethane Walden Inversion |
| Summary: | The reactions here explored are microscopic analogs of Newton cradle: left thing attack, right thing leaves and central thing remains unaffected. We have studied symmetric S2 reactions, X = N or E, where the attacking and leaving molecules are the same: HN, HB, HC and the central molecules are HB (S2@B), HN (S2) or HC (S2@C). Non-symmetric reactions with different initial and final complexes were also studied and examples where the elements of the lateral molecules differ, P vs N. |
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