Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation

We demonstrate for the first time, the real lifetime response of mixed halide perovskite solar cells (PSCs) for >1000 h under outdoor conditions and the exceptional photoresponse observed at low-light intensities attributed to the ionic-electronic nature of the material. The investigated devices...

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Autores: Reyna, Yegraf, Salado, Manuel, Kazim, Samrana, Pérez-Tomás, Amador, Ahmad, Shahzada, Lira-Cantú, Mónica
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/159838
Acceso en línea:http://hdl.handle.net/10261/159838
Access Level:acceso abierto
Palabra clave:Outdoor analyses
Hybrid solar cells
Stability
ISOS protocols
Halide perovskite solar cells
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spelling Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiationReyna, YegrafSalado, ManuelKazim, SamranaPérez-Tomás, AmadorAhmad, ShahzadaLira-Cantú, MónicaOutdoor analysesHybrid solar cellsStabilityISOS protocolsHalide perovskite solar cellsWe demonstrate for the first time, the real lifetime response of mixed halide perovskite solar cells (PSCs) for >1000 h under outdoor conditions and the exceptional photoresponse observed at low-light intensities attributed to the ionic-electronic nature of the material. The investigated devices were fabricated by utilizing mixed perovskites containing formamidinium (FA) and methylammonium (MA) cations, in a one step solution-process method through a solvent engineering approach. The devices’ architecture is FTO/TiO (blocking layer) TiO (mesoporous)/FAPbIMAPbBr/Spiro-OMeTAD/Au. Notably, low short circuit current (J) was observed at low light intensities (<50 W/m) together with high open circuit potential build-up, which resulted in high PCEs. This response is in agreement with a “double electronic-ionic transport” model of the halide perovskite where the ionic component dominates at low light intensities and the electronic component dictates at high light irradiances. Our results highlight the exceptional stability of mixed MA/FA mesoscopic PSCs when operated for >1000 h under real outdoor conditions and the strong ionic component observed at low light irradiation.CN2 acknowledges the support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program under Grant SEV-2013-0295, for the Grants ENE2013-48816-C5-4-R, ENE2016-79282-C5-2-R and the Nanoselect Excelence Network MAT2015-68994-REDC. To the Agència de Gestió d'Ajuts Universitaris i de Recerca for the support to consolidated Catalonia research group 2014SGR-1212 and the Xarxa de Referència en Materials Avançats per a l'Energia (Xarmae). To the COST Action StableNextSol ProjectMP1307. To CONACYT for the PhD awarded to Y.R.Peer ReviewedElsevierGeneralitat de CatalunyaMinisterio de Economía y Competitividad (España)Consejo Nacional de Ciencia y Tecnología (México)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2018201820162018info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/159838reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2013-48816-C5-4-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2016-79282-C5-2-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-68994-REDCinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295https://doi.org/10.1016/j.nanoen.2016.10.053Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1598382026-05-22T06:33:51Z
dc.title.none.fl_str_mv Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
title Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
spellingShingle Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
Reyna, Yegraf
Outdoor analyses
Hybrid solar cells
Stability
ISOS protocols
Halide perovskite solar cells
title_short Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
title_full Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
title_fullStr Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
title_full_unstemmed Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
title_sort Performance and stability of mixed FAPbI3(0.85)MAPbBr3(0.15) halide perovskite solar cells under outdoor conditions and the effect of low light irradiation
dc.creator.none.fl_str_mv Reyna, Yegraf
Salado, Manuel
Kazim, Samrana
Pérez-Tomás, Amador
Ahmad, Shahzada
Lira-Cantú, Mónica
author Reyna, Yegraf
author_facet Reyna, Yegraf
Salado, Manuel
Kazim, Samrana
Pérez-Tomás, Amador
Ahmad, Shahzada
Lira-Cantú, Mónica
author_role author
author2 Salado, Manuel
Kazim, Samrana
Pérez-Tomás, Amador
Ahmad, Shahzada
Lira-Cantú, Mónica
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Generalitat de Catalunya
Ministerio de Economía y Competitividad (España)
Consejo Nacional de Ciencia y Tecnología (México)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Outdoor analyses
Hybrid solar cells
Stability
ISOS protocols
Halide perovskite solar cells
topic Outdoor analyses
Hybrid solar cells
Stability
ISOS protocols
Halide perovskite solar cells
description We demonstrate for the first time, the real lifetime response of mixed halide perovskite solar cells (PSCs) for >1000 h under outdoor conditions and the exceptional photoresponse observed at low-light intensities attributed to the ionic-electronic nature of the material. The investigated devices were fabricated by utilizing mixed perovskites containing formamidinium (FA) and methylammonium (MA) cations, in a one step solution-process method through a solvent engineering approach. The devices’ architecture is FTO/TiO (blocking layer) TiO (mesoporous)/FAPbIMAPbBr/Spiro-OMeTAD/Au. Notably, low short circuit current (J) was observed at low light intensities (<50 W/m) together with high open circuit potential build-up, which resulted in high PCEs. This response is in agreement with a “double electronic-ionic transport” model of the halide perovskite where the ionic component dominates at low light intensities and the electronic component dictates at high light irradiances. Our results highlight the exceptional stability of mixed MA/FA mesoscopic PSCs when operated for >1000 h under real outdoor conditions and the strong ionic component observed at low light irradiation.
publishDate 2016
dc.date.none.fl_str_mv 2016
2018
2018
2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/159838
url http://hdl.handle.net/10261/159838
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2013-48816-C5-4-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2016-79282-C5-2-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-68994-REDC
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295
https://doi.org/10.1016/j.nanoen.2016.10.053
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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