Trispyrazolylborate coinage metals complexes : structural features and catalytic transformations
Tris(pyrazolyl)borates (Tpx) have become one of the most broadly used polydentate anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in 1966. Herein we present a review of the main structural features of Group 11 metal complexes with Tpx ligands, as well as thei...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universidad de Huelva (UHU) |
| Repositorio: | Arias Montano. Repositorio Institucional de la Universidad de Huelva |
| Idioma: | inglés |
| OAI Identifier: | oai:ariasmontano.uhu.es:10272/16200 |
| Acceso en línea: | http://hdl.handle.net/10272/16200 |
| Access Level: | acceso abierto |
| Palabra clave: | Group 11 metal complexes Tris(pyrazolyl)borate Steric hindrance Electronic features homogeneous catalysis |
| Sumario: | Tris(pyrazolyl)borates (Tpx) have become one of the most broadly used polydentate anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in 1966. Herein we present a review of the main structural features of Group 11 metal complexes with Tpx ligands, as well as their catalytic properties, can be controlled by ligand steric and electronic factors. |
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