Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides

Transition metal phosphides have great potential to optimize a number of functionalities in several energy conversion and storage applications, particularly when nanostructured or in nanoparticle form. However, the synthesis of transition metal phosphide nanoparticles and its scalability is often li...

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Autores: Liu, Junfeng|||0000-0003-3164-6472, Meyns, Michaela|||0000-0003-2476-9001, Zhang, Ting|||0000-0002-0317-9662, Arbiol i Cobos, Jordi|||0000-0002-0695-1726, Cabot i Codina, Andreu|||0000-0002-7533-3251, Shavel, Alexey|||0000-0002-3995-0391
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:215008
Acesso em linha:https://ddd.uab.cat/record/215008
https://dx.doi.org/urn:doi:10.1021/acs.chemmater.8b00290
Access Level:acceso abierto
Palavra-chave:Cost-effective production
Energy conversion and storages
Experimental parameters
Metal phosphides
Organic ligands
Phosphorus sources
Transition metal phosphide
Triphenyl phosphite
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spelling Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphidesLiu, Junfeng|||0000-0003-3164-6472Meyns, Michaela|||0000-0003-2476-9001Zhang, Ting|||0000-0002-0317-9662Arbiol i Cobos, Jordi|||0000-0002-0695-1726Cabot i Codina, Andreu|||0000-0002-7533-3251Shavel, Alexey|||0000-0002-3995-0391Cost-effective productionEnergy conversion and storagesExperimental parametersMetal phosphidesOrganic ligandsPhosphorus sourcesTransition metal phosphideTriphenyl phosphiteTransition metal phosphides have great potential to optimize a number of functionalities in several energy conversion and storage applications, particularly when nanostructured or in nanoparticle form. However, the synthesis of transition metal phosphide nanoparticles and its scalability is often limited by the toxicity, air sensitivity, and high cost of the reagents used. We present here a simple, scalable, and cost-effective "heating up" procedure to produce metal phosphides using inexpensive, low-toxicity, and air-stable triphenyl phosphite as source of phosphorus and chlorides as metal precursors. This procedure allows the synthesis of a variety of phosphide nanoparticles, including phosphides of Ni, Co, and Cu. The use of carbonyl metal precursors further allowed the synthesis of FeP and MoP nanoparticles. The fact that minor modifications in the experimental parameters allowed producing nanoparticles with different compositions and even to tune their size and shape shows the high potential and versatility of the triphenyl phosphite precursor and the presented method. We also detail here a methodology to displace organic ligands from the surface of phosphide nanoparticles, which is a key step toward their application in energy conversion and storage systems. 22018-01-0120182018-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/215008https://dx.doi.org/urn:doi:10.1021/acs.chemmater.8b00290reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2017-85087-C3-3-RAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-77798-C4-3-RMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-327open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2150082026-06-06T12:50:31Z
dc.title.none.fl_str_mv Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
title Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
spellingShingle Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
Liu, Junfeng|||0000-0003-3164-6472
Cost-effective production
Energy conversion and storages
Experimental parameters
Metal phosphides
Organic ligands
Phosphorus sources
Transition metal phosphide
Triphenyl phosphite
title_short Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
title_full Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
title_fullStr Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
title_full_unstemmed Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
title_sort Triphenyl phosphite as the phosphorus source for the scalable and cost-effective production of transition metal phosphides
dc.creator.none.fl_str_mv Liu, Junfeng|||0000-0003-3164-6472
Meyns, Michaela|||0000-0003-2476-9001
Zhang, Ting|||0000-0002-0317-9662
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Cabot i Codina, Andreu|||0000-0002-7533-3251
Shavel, Alexey|||0000-0002-3995-0391
author Liu, Junfeng|||0000-0003-3164-6472
author_facet Liu, Junfeng|||0000-0003-3164-6472
Meyns, Michaela|||0000-0003-2476-9001
Zhang, Ting|||0000-0002-0317-9662
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Cabot i Codina, Andreu|||0000-0002-7533-3251
Shavel, Alexey|||0000-0002-3995-0391
author_role author
author2 Meyns, Michaela|||0000-0003-2476-9001
Zhang, Ting|||0000-0002-0317-9662
Arbiol i Cobos, Jordi|||0000-0002-0695-1726
Cabot i Codina, Andreu|||0000-0002-7533-3251
Shavel, Alexey|||0000-0002-3995-0391
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Cost-effective production
Energy conversion and storages
Experimental parameters
Metal phosphides
Organic ligands
Phosphorus sources
Transition metal phosphide
Triphenyl phosphite
topic Cost-effective production
Energy conversion and storages
Experimental parameters
Metal phosphides
Organic ligands
Phosphorus sources
Transition metal phosphide
Triphenyl phosphite
description Transition metal phosphides have great potential to optimize a number of functionalities in several energy conversion and storage applications, particularly when nanostructured or in nanoparticle form. However, the synthesis of transition metal phosphide nanoparticles and its scalability is often limited by the toxicity, air sensitivity, and high cost of the reagents used. We present here a simple, scalable, and cost-effective "heating up" procedure to produce metal phosphides using inexpensive, low-toxicity, and air-stable triphenyl phosphite as source of phosphorus and chlorides as metal precursors. This procedure allows the synthesis of a variety of phosphide nanoparticles, including phosphides of Ni, Co, and Cu. The use of carbonyl metal precursors further allowed the synthesis of FeP and MoP nanoparticles. The fact that minor modifications in the experimental parameters allowed producing nanoparticles with different compositions and even to tune their size and shape shows the high potential and versatility of the triphenyl phosphite precursor and the presented method. We also detail here a methodology to displace organic ligands from the surface of phosphide nanoparticles, which is a key step toward their application in energy conversion and storage systems.
publishDate 2018
dc.date.none.fl_str_mv 2
2018-01-01
2018
2018-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/215008
https://dx.doi.org/urn:doi:10.1021/acs.chemmater.8b00290
url https://ddd.uab.cat/record/215008
https://dx.doi.org/urn:doi:10.1021/acs.chemmater.8b00290
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2017-85087-C3-3-R
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 ENE2016-77798-C4-3-R
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2013-0295
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-327
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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