Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene

Several supported liquid-phase (SLP) catalysts with immobilized Rh-biphephos complexes on monolithic supports were prepared and applied for continuous gas-phase hydroformylation (HyFo) of 1-butene. The support comprised macroporous monolithic silicon carbide (SiC) with deposited silica nanoparticles...

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Authors: Madani, M., Schill, L., Zahrtmann, N., Portela, Raquel, Arsenjuk, L., Franke, R., Fehrmann, R., Riisager, A.
Format: article
Status:Published version
Publication Date:2023
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/359520
Online Access:http://hdl.handle.net/10261/359520
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149271252&doi=10.1007%2fs11244-023-01792-w&partnerID=40&md5=8bcd3b57f3e588019b5aa940366bf5a5
Access Level:Open access
Keyword:Heterogenization
Hydroformylation
Monolith
Porosity
Silicon carbide
SLP catalyst
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spelling Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-ButeneMadani, M.Schill, L.Zahrtmann, N.Portela, RaquelArsenjuk, L.Franke, R.Fehrmann, R.Riisager, A.HeterogenizationHydroformylationMonolithPorositySilicon carbideSLP catalystSeveral supported liquid-phase (SLP) catalysts with immobilized Rh-biphephos complexes on monolithic supports were prepared and applied for continuous gas-phase hydroformylation (HyFo) of 1-butene. The support comprised macroporous monolithic silicon carbide (SiC) with deposited silica nanoparticles (NPs) in order to provide mesopores with enhanced capillary forces to retain the liquid-phase. Variable parameters were examined for the monolithic SiC supports, including size and loading of deposited silica NPs and intermediate calcination between silica deposition steps to obtain the most efficient support configuration for the SLP system. The SLP catalysts with larger deposited silica NPs gave higher catalytic activity (i.e. 1-butene conversion and turnover frequency) compared to the supports with smaller sized silica NPs. However, the selectivity towards the preferred linear aldehyde was higher in the SLP catalysts with supports containing less silica with small silica NPs. Importantly, the prepared SLP catalyst systems showed long-term stability in HyFo with negligible formation of high boiling aldol condensation products. © 2023, The Author(s).Funding Horizon 2020, 869896Peer reviewedSpringerEuropean CommissionConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/359520https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149271252&doi=10.1007%2fs11244-023-01792-w&partnerID=40&md5=8bcd3b57f3e588019b5aa940366bf5a5reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/869896Topics in Catalysishttps://doi.org/10.1007/s11244-023-01792-wSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3595202026-05-22T06:33:51Z
dc.title.none.fl_str_mv Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
title Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
spellingShingle Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
Madani, M.
Heterogenization
Hydroformylation
Monolith
Porosity
Silicon carbide
SLP catalyst
title_short Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
title_full Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
title_fullStr Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
title_full_unstemmed Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
title_sort Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
dc.creator.none.fl_str_mv Madani, M.
Schill, L.
Zahrtmann, N.
Portela, Raquel
Arsenjuk, L.
Franke, R.
Fehrmann, R.
Riisager, A.
author Madani, M.
author_facet Madani, M.
Schill, L.
Zahrtmann, N.
Portela, Raquel
Arsenjuk, L.
Franke, R.
Fehrmann, R.
Riisager, A.
author_role author
author2 Schill, L.
Zahrtmann, N.
Portela, Raquel
Arsenjuk, L.
Franke, R.
Fehrmann, R.
Riisager, A.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Heterogenization
Hydroformylation
Monolith
Porosity
Silicon carbide
SLP catalyst
topic Heterogenization
Hydroformylation
Monolith
Porosity
Silicon carbide
SLP catalyst
description Several supported liquid-phase (SLP) catalysts with immobilized Rh-biphephos complexes on monolithic supports were prepared and applied for continuous gas-phase hydroformylation (HyFo) of 1-butene. The support comprised macroporous monolithic silicon carbide (SiC) with deposited silica nanoparticles (NPs) in order to provide mesopores with enhanced capillary forces to retain the liquid-phase. Variable parameters were examined for the monolithic SiC supports, including size and loading of deposited silica NPs and intermediate calcination between silica deposition steps to obtain the most efficient support configuration for the SLP system. The SLP catalysts with larger deposited silica NPs gave higher catalytic activity (i.e. 1-butene conversion and turnover frequency) compared to the supports with smaller sized silica NPs. However, the selectivity towards the preferred linear aldehyde was higher in the SLP catalysts with supports containing less silica with small silica NPs. Importantly, the prepared SLP catalyst systems showed long-term stability in HyFo with negligible formation of high boiling aldol condensation products. © 2023, The Author(s).
publishDate 2023
dc.date.none.fl_str_mv 2023
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/359520
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149271252&doi=10.1007%2fs11244-023-01792-w&partnerID=40&md5=8bcd3b57f3e588019b5aa940366bf5a5
url http://hdl.handle.net/10261/359520
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85149271252&doi=10.1007%2fs11244-023-01792-w&partnerID=40&md5=8bcd3b57f3e588019b5aa940366bf5a5
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/869896
Topics in Catalysis
https://doi.org/10.1007/s11244-023-01792-w
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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