Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst

The development of a heterogeneous one-component bifunctional catalyst system able to catalyse the conversion of carbon dioxide and oxiranes to organic cyclic carbonates at low temperature (45 oC) is reported. The bifunctional system can be easily recycled and reactivated when required. When compare...

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Autores: Whiteoak, Christopher J., Henseler, Andrea H., Ayats, Carles, Kleij, Arjan W., Pericà, Miquel A.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2013
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/356256
Acceso en línea:http://hdl.handle.net/2072/356256
https://doi.org/10.1039/C3GC41919C
Access Level:acceso abierto
Palabra clave:54
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spelling Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported OrganocatalystWhiteoak, Christopher J.Henseler, Andrea H.Ayats, CarlesKleij, Arjan W.Pericà, Miquel A.54The development of a heterogeneous one-component bifunctional catalyst system able to catalyse the conversion of carbon dioxide and oxiranes to organic cyclic carbonates at low temperature (45 oC) is reported. The bifunctional system can be easily recycled and reactivated when required. When compared with other heterogeneous organocatalysts for the same transformation, the reported catalyst is active at 10 much milder temperatures, thus emphasising the optimal sustainability profile of the new catalyst system.2013info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion1552 p.application/pdfhttp://hdl.handle.net/2072/356256https://doi.org/10.1039/C3GC41919CRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésL'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3562562026-05-29T05:05:01Z
dc.title.none.fl_str_mv Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
title Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
spellingShingle Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
Whiteoak, Christopher J.
54
title_short Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
title_full Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
title_fullStr Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
title_full_unstemmed Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
title_sort Conversion of Oxiranes and CO2 to Organic Cyclic Carbonates using a Recyclable, Bifunctional Polystyrene-Supported Organocatalyst
dc.creator.none.fl_str_mv Whiteoak, Christopher J.
Henseler, Andrea H.
Ayats, Carles
Kleij, Arjan W.
Pericà, Miquel A.
author Whiteoak, Christopher J.
author_facet Whiteoak, Christopher J.
Henseler, Andrea H.
Ayats, Carles
Kleij, Arjan W.
Pericà, Miquel A.
author_role author
author2 Henseler, Andrea H.
Ayats, Carles
Kleij, Arjan W.
Pericà, Miquel A.
author2_role author
author
author
author
dc.subject.none.fl_str_mv 54
topic 54
description The development of a heterogeneous one-component bifunctional catalyst system able to catalyse the conversion of carbon dioxide and oxiranes to organic cyclic carbonates at low temperature (45 oC) is reported. The bifunctional system can be easily recycled and reactivated when required. When compared with other heterogeneous organocatalysts for the same transformation, the reported catalyst is active at 10 much milder temperatures, thus emphasising the optimal sustainability profile of the new catalyst system.
publishDate 2013
dc.date.none.fl_str_mv 2013
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/356256
https://doi.org/10.1039/C3GC41919C
url http://hdl.handle.net/2072/356256
https://doi.org/10.1039/C3GC41919C
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1552 p.
application/pdf
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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