Unravelling the CO2 capture and conversion mechanism of a NiRu-Na2O switchable dual-function material in various CO2 utilisation reactions
Time-resolved operando DRIFTS-MS was performed to elucidate the CO2 capture and conversion mechanisms of a NiRuNa/CeAl DFM in CO2 methanation, reverse water-gas shift, and dry reforming of methane. CO2 was captured mainly in the form of carbonyls and bidentate carbonates, and a spillover mechanism o...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/356207 |
| Acceso en línea: | http://hdl.handle.net/10261/356207 https://api.elsevier.com/content/abstract/scopus_id/85161512504 |
| Access Level: | acceso abierto |
| Palabra clave: | http://metadata.un.org/sdg/13 Take urgent action to combat climate change and its impacts |
| Sumario: | Time-resolved operando DRIFTS-MS was performed to elucidate the CO2 capture and conversion mechanisms of a NiRuNa/CeAl DFM in CO2 methanation, reverse water-gas shift, and dry reforming of methane. CO2 was captured mainly in the form of carbonyls and bidentate carbonates, and a spillover mechanism occurred to obtain the desired products. |
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