Palladium-Catalyzed Oxidative Arene C-H Alkenylation Reactions Involving Olefins
The Palladium-catalyzed selective C-H alkenylation reaction has been established as a central synthetic transformation to enable the construction of carbon–carbon bonds in an efficient, atom-economical, and environmentally friendly way. It provides a powerful alternative to classical cross-coupling...
| Autores: | , , |
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| Tipo de documento: | artigo |
| Data de publicação: | 2022 |
| País: | España |
| Recursos: | Universidad del País Vasco |
| Repositório: | Addi. Archivo Digital para la Docencia y la Investigación |
| OAI Identifier: | oai:addi.ehu.eus:10810/63177 |
| Acesso em linha: | http://hdl.handle.net/10810/63177 |
| Access Level: | Acceso aberto |
| Palavra-chave: | palladium C-H activation alkenylation catalysis |
| Resumo: | The Palladium-catalyzed selective C-H alkenylation reaction has been established as a central synthetic transformation to enable the construction of carbon–carbon bonds in an efficient, atom-economical, and environmentally friendly way. It provides a powerful alternative to classical cross-coupling reactions for the construction of conjugated organic molecules, including late-stage functionalization. The knowledge of mechanisms, the use of different strategies to control site-selectivity, and the development of efficient chiral catalysts for C-H alkenylation reactions has expanded the application of this tool for the synthesis of molecules of increased complexity |
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