Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation

Micelles generated upon dissolving surfactants in water can be employed as nano-vessels for catalytic transformations, in the so-called micellar catalysis methodology. This review is focused onto the use of micellar catalysis in the context of the catalytic functionalization of carbon-hydrogen bonds...

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Detalhes bibliográficos
Autores: Borrego, Elena, Caballero Bevia, Ana, Pérez Romero, Pedro José
Formato: artículo
Fecha de publicación:2022
País:España
Recursos:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/21358
Acesso em linha:https://hdl.handle.net/10272/21358
Access Level:acceso abierto
Palavra-chave:Arylation
Catalysts
Micelles
Organic reactions
Surfactants
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spelling Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond FormationBorrego, ElenaCaballero Bevia, AnaPérez Romero, Pedro JoséArylationCatalystsMicellesOrganic reactionsSurfactantsMicelles generated upon dissolving surfactants in water can be employed as nano-vessels for catalytic transformations, in the so-called micellar catalysis methodology. This review is focused onto the use of micellar catalysis in the context of the catalytic functionalization of carbon-hydrogen bonds. The micelles accumulate catalyst and reactants in their inner volume in such a high local concentration that kinetics are favored. The consequence is that in most cases, processes that in conventional organic solvents require high temperatures and long reaction times are achieved in milder conditions when micellar catalysis is employed.American Chemical Society20222022-11-2820222022-11-28journal articlehttp://purl.org/coar/resource_type/c_6501info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10272/21358reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelvainstname:Universidad de Huelva (UHU)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:ariasmontano.uhu.es:10272/213582026-06-02T14:58:11Z
dc.title.none.fl_str_mv Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
title Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
spellingShingle Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
Borrego, Elena
Arylation
Catalysts
Micelles
Organic reactions
Surfactants
title_short Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
title_full Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
title_fullStr Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
title_full_unstemmed Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
title_sort Micellar Catalysis as a Tool for C-H Bond Functionalization To-ward C-C Bond Formation
dc.creator.none.fl_str_mv Borrego, Elena
Caballero Bevia, Ana
Pérez Romero, Pedro José
author Borrego, Elena
author_facet Borrego, Elena
Caballero Bevia, Ana
Pérez Romero, Pedro José
author_role author
author2 Caballero Bevia, Ana
Pérez Romero, Pedro José
author2_role author
author
dc.contributor.none.fl_str_mv
dc.subject.none.fl_str_mv Arylation
Catalysts
Micelles
Organic reactions
Surfactants
topic Arylation
Catalysts
Micelles
Organic reactions
Surfactants
description Micelles generated upon dissolving surfactants in water can be employed as nano-vessels for catalytic transformations, in the so-called micellar catalysis methodology. This review is focused onto the use of micellar catalysis in the context of the catalytic functionalization of carbon-hydrogen bonds. The micelles accumulate catalyst and reactants in their inner volume in such a high local concentration that kinetics are favored. The consequence is that in most cases, processes that in conventional organic solvents require high temperatures and long reaction times are achieved in milder conditions when micellar catalysis is employed.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-11-28
2022
2022-11-28
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10272/21358
url https://hdl.handle.net/10272/21358
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelva
instname:Universidad de Huelva (UHU)
instname_str Universidad de Huelva (UHU)
reponame_str Arias Montano. Repositorio Institucional de la Universidad de Huelva
collection Arias Montano. Repositorio Institucional de la Universidad de Huelva
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812455

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