[All]-S,S-dioxide Oligo-Thienylenevinylenes: Synthesis and Structural/Electronic Shapes from Their Molecular Force Fields

Oligo-S,S-dioxothienylenevinylenes have been prepared by transferring oxygen atoms to the sulfur atoms using the HOF·CH3CN complex. Their photophysical properties are presented in comparison with their thio phenevinylene congeners. Together with their vibrational properties and molecular force field...

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Detalles Bibliográficos
Autores: Aharon, Cheryl, García Guijarro, Fernando, Medina, Samara, Ramírez, Francisco J., Caballero Briceño, Rubén, Casado Cordón, Juan, Langa de la Puente, Fernando, Rozen, Shlomo
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/28993
Acceso en línea:http://hdl.handle.net/10578/28993
Access Level:acceso abierto
Palabra clave:Oligo-S,S-dioxothienylenevinylenes
Molecular Force Fields
Descripción
Sumario:Oligo-S,S-dioxothienylenevinylenes have been prepared by transferring oxygen atoms to the sulfur atoms using the HOF·CH3CN complex. Their photophysical properties are presented in comparison with their thio phenevinylene congeners. Together with their vibrational properties and molecular force fields, this study allows for the interpretation of the alteration of aromaticity and inter-ring exocyclic p-conjugation in this series.