Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon

[EN] The development of heterogeneous catalysts for hydrocarbon oxidation by molecular oxygen as oxidant is an area of increasing interest from academia and chemical industry points of views. Herein, the catalytic activity of two-dimensional (2D) porphyrin metal -organic frameworks (MOFs) constitute...

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Autores: Uscategui-Linares, Andrés Felipe|||0000-0003-2448-9966, Navalón Oltra, Sergio|||0000-0001-8423-0759, Albero-Sancho, Josep|||0000-0002-4841-7206, García Gómez, Hermenegildo|||0000-0002-9664-493X, Santiago-Portillo, Andrea, Dhakshinamoorthy, Amarajothi, Parvulescu, Vasile
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/214921
Acceso en línea:https://riunet.upv.es/handle/10251/214921
Access Level:acceso abierto
Palabra clave:Aerobic oxidation
Indane
Heterogeneous catalysis
Metal organic frameworks
Two-dimensional
QUIMICA ORGANICA
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oai_identifier_str oai:riunet.upv.es:10251/214921
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
title Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
spellingShingle Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
Uscategui-Linares, Andrés Felipe|||0000-0003-2448-9966
Aerobic oxidation
Indane
Heterogeneous catalysis
Metal organic frameworks
Two-dimensional
QUIMICA ORGANICA
title_short Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
title_full Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
title_fullStr Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
title_full_unstemmed Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
title_sort Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbon
dc.creator.none.fl_str_mv Uscategui-Linares, Andrés Felipe|||0000-0003-2448-9966
Navalón Oltra, Sergio|||0000-0001-8423-0759
Albero-Sancho, Josep|||0000-0002-4841-7206
García Gómez, Hermenegildo|||0000-0002-9664-493X
Santiago-Portillo, Andrea
Dhakshinamoorthy, Amarajothi
Parvulescu, Vasile
author Uscategui-Linares, Andrés Felipe|||0000-0003-2448-9966
author_facet Uscategui-Linares, Andrés Felipe|||0000-0003-2448-9966
Navalón Oltra, Sergio|||0000-0001-8423-0759
Albero-Sancho, Josep|||0000-0002-4841-7206
García Gómez, Hermenegildo|||0000-0002-9664-493X
Santiago-Portillo, Andrea
Dhakshinamoorthy, Amarajothi
Parvulescu, Vasile
author_role author
author2 Navalón Oltra, Sergio|||0000-0001-8423-0759
Albero-Sancho, Josep|||0000-0002-4841-7206
García Gómez, Hermenegildo|||0000-0002-9664-493X
Santiago-Portillo, Andrea
Dhakshinamoorthy, Amarajothi
Parvulescu, Vasile
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Instituto Universitario Mixto de Tecnología Química
Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Grupo de Fotoquímica Heterogénea y Medioambiental
Generalitat Valenciana
Agencia Estatal de Investigación
European Regional Development Fund
Ministerio de Ciencia e Innovación
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Aerobic oxidation
Indane
Heterogeneous catalysis
Metal organic frameworks
Two-dimensional
QUIMICA ORGANICA
topic Aerobic oxidation
Indane
Heterogeneous catalysis
Metal organic frameworks
Two-dimensional
QUIMICA ORGANICA
description [EN] The development of heterogeneous catalysts for hydrocarbon oxidation by molecular oxygen as oxidant is an area of increasing interest from academia and chemical industry points of views. Herein, the catalytic activity of two-dimensional (2D) porphyrin metal -organic frameworks (MOFs) constituted by Co 2 + , Cu 2 + or Mn 3 + as transition metal ions coordinated to tetra(4-carboxyphenyl)porphyrin (TCPP) organic ligand as heterogeneous catalysts for the aerobic oxidation of benzylic hydrocarbon oxidation is reported. Selective radical quenching experiments and in -situ Raman measurements reveal the formation of superoxide/hydroperoxide and hydroxyl radicals during the catalytic reaction using Co-CoTCPP.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-07-15
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/214921
url https://riunet.upv.es/handle/10251/214921
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-123856OB-I00 FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOS
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-S CENTRO DE EXCELENCIA SEVERO OCHO INSTITUTO DE TECNOLOGIA QUIMICA (ITQ)
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038
Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 RYC2021-031006-I
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial - Sin obra derivada (by-nc-nd)
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling Two-dimensional Co-based porphyrin metal-organic framework as heterogeneous catalyst for the aerobic oxidation of benzylic hydrocarbonUscategui-Linares, Andrés Felipe|||0000-0003-2448-9966Navalón Oltra, Sergio|||0000-0001-8423-0759Albero-Sancho, Josep|||0000-0002-4841-7206García Gómez, Hermenegildo|||0000-0002-9664-493XSantiago-Portillo, AndreaDhakshinamoorthy, AmarajothiParvulescu, VasileAerobic oxidationIndaneHeterogeneous catalysisMetal organic frameworksTwo-dimensionalQUIMICA ORGANICA[EN] The development of heterogeneous catalysts for hydrocarbon oxidation by molecular oxygen as oxidant is an area of increasing interest from academia and chemical industry points of views. Herein, the catalytic activity of two-dimensional (2D) porphyrin metal -organic frameworks (MOFs) constituted by Co 2 + , Cu 2 + or Mn 3 + as transition metal ions coordinated to tetra(4-carboxyphenyl)porphyrin (TCPP) organic ligand as heterogeneous catalysts for the aerobic oxidation of benzylic hydrocarbon oxidation is reported. Selective radical quenching experiments and in -situ Raman measurements reveal the formation of superoxide/hydroperoxide and hydroxyl radicals during the catalytic reaction using Co-CoTCPP.Financial support the Spanish Ministry of Science and Innovation (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Generation EU, through the Conselleria de Innovacion, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Universities, financed by the European Union, NextGeneration EU) .r (Severo Ochoa CEX2021-1230-S financed support by MCIN/AEI/10.13039/501100011033) , and Generalitat Valenciana (Prometeu 2021-038 and MFA-2022-023 financed by European Union-Next Gen-eration EU, through the Conselleria de Innovaci on, Universidades, Ciencia y Sociedad Digital) are gratefully acknowledged. J.A. thanks the Spanish Ministry of Science and Innovation for a Ramon y Cajal research associate contract (RYC2021-031006-I financed support by MCIN/AEI/10.13039/501100011033 and by European Union/NextGenerationEU/PRTR) . S.N. thanks the support of grant PID2021-123856OBI00 funded by MICIU/AEI/10.13039/501100011033 and by ERDF A way of making Europe. A.D. is beneficiary of a grant Maria Zambrano in Universitat Politecnica de Valencia within the framework of the grants for the retraining in the Spanish university system (Spanish Ministry of Uni-versities, financed by the European Union, NextGeneration EU) .ElsevierInstituto Universitario Mixto de Tecnología QuímicaDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialGrupo de Fotoquímica Heterogénea y MedioambientalGeneralitat ValencianaAgencia Estatal de InvestigaciónEuropean Regional Development FundMinisterio de Ciencia e InnovaciónUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-07-15journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/214921reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-123856OB-I00 FOTOCATALIZADORES MULTIFUNCIONALES BASADOS EN MATERIALES HIBRIDOS METAL-ORGANICO PARA LA REDUCCION SELECTIVA DE CO2 IMPULSADA POR LA ENERGIA SOLAR A COMBUSTIBLES Y PRODUCTOSAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 CEX2021-001230-S CENTRO DE EXCELENCIA SEVERO OCHO INSTITUTO DE TECNOLOGIA QUIMICA (ITQ)Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEO%2F2021%2F038Generalitat Valenciana https://doi.org/10.13039/501100003359 MFA%2F2022%2F023Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 RYC2021-031006-Iopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial - Sin obra derivada (by-nc-nd) http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2149212026-06-13T07:49:27Z
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