Coassembly of complementary polyhedral metal-organic framework particles into binary ordered superstructures

Here we report the formation of a 3D NaCl-type binary porous superstructure via coassembly of two colloidal polyhedral metal–organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated...

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Detalles Bibliográficos
Autores: Meng, Lingxin, Fonseca, Javier, Sánchez-Naya, Roberto, Ghadiri, Amir Mohammad, Imaz, Inhar, Maspoch, Daniel
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/375230
Acceso en línea:http://hdl.handle.net/10261/375230
Access Level:acceso abierto
Descripción
Sumario:Here we report the formation of a 3D NaCl-type binary porous superstructure via coassembly of two colloidal polyhedral metal–organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures comprising particles of various sizes, shapes, porosities, and chemical compositions.