Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene

Visualizing chemical reactions as they occur requires atomic spatial and femtosecond temporal resolution. Here, we report imaging of the molecular structure of acetylene (C2H2) 9 femtoseconds after ionization. Using mid-infrared laser–induced electron diffraction (LIED), we obtained snapshots as a p...

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Detalhes bibliográficos
Autores: Wolter, B., Pullen, M. G., Le, A.-T., Baudisch, M., Doblhoff-Dier, K., Senftleben, A., Hemmer, M., Schröter, C. D., Ullrich, J., Pfeifer, T., Moshammer, R., Gräfe, S., Vendrell, O., Lin, C. D., Biegert, Jens
Formato: artículo
Fecha de publicación:2016
País:España
Recursos:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/105958
Acesso em linha:https://hdl.handle.net/2117/105958
Access Level:acceso abierto
Palavra-chave:Acetylene
acetylene
Acetilè
Àrees temàtiques de la UPC::Física
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spelling Ultrafast electron diffraction imaging of bond breaking in di-ionized acetyleneWolter, B.Pullen, M. G.Le, A.-T.Baudisch, M.Doblhoff-Dier, K.Senftleben, A.Hemmer, M.Schröter, C. D.Ullrich, J.Pfeifer, T.Moshammer, R.Gräfe, S.Vendrell, O.Lin, C. D.Biegert, JensAcetyleneacetyleneAcetilèÀrees temàtiques de la UPC::FísicaVisualizing chemical reactions as they occur requires atomic spatial and femtosecond temporal resolution. Here, we report imaging of the molecular structure of acetylene (C2H2) 9 femtoseconds after ionization. Using mid-infrared laser–induced electron diffraction (LIED), we obtained snapshots as a proton departs the [C2H2]2+ ion. By introducing an additional laser field, we also demonstrate control over the ultrafast dissociation process and resolve different bond dynamics for molecules oriented parallel versus perpendicular to the LIED field. These measurements are in excellent agreement with a quantum chemical description of field-dressed molecular dynamicsScience20162016-10-1620172017-06-28journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/105958reponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)InglésengEuropean Commission http://doi.org/10.13039/100010661 Horizon 2020 Framework Programme 654148 The Integrated Initiative of European Laser Research Infrastructuresopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivs 3.0 Spainhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/1059582026-05-27T15:37:01Z
dc.title.none.fl_str_mv Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
title Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
spellingShingle Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
Wolter, B.
Acetylene
acetylene
Acetilè
Àrees temàtiques de la UPC::Física
title_short Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
title_full Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
title_fullStr Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
title_full_unstemmed Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
title_sort Ultrafast electron diffraction imaging of bond breaking in di-ionized acetylene
dc.creator.none.fl_str_mv Wolter, B.
Pullen, M. G.
Le, A.-T.
Baudisch, M.
Doblhoff-Dier, K.
Senftleben, A.
Hemmer, M.
Schröter, C. D.
Ullrich, J.
Pfeifer, T.
Moshammer, R.
Gräfe, S.
Vendrell, O.
Lin, C. D.
Biegert, Jens
author Wolter, B.
author_facet Wolter, B.
Pullen, M. G.
Le, A.-T.
Baudisch, M.
Doblhoff-Dier, K.
Senftleben, A.
Hemmer, M.
Schröter, C. D.
Ullrich, J.
Pfeifer, T.
Moshammer, R.
Gräfe, S.
Vendrell, O.
Lin, C. D.
Biegert, Jens
author_role author
author2 Pullen, M. G.
Le, A.-T.
Baudisch, M.
Doblhoff-Dier, K.
Senftleben, A.
Hemmer, M.
Schröter, C. D.
Ullrich, J.
Pfeifer, T.
Moshammer, R.
Gräfe, S.
Vendrell, O.
Lin, C. D.
Biegert, Jens
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Acetylene
acetylene
Acetilè
Àrees temàtiques de la UPC::Física
topic Acetylene
acetylene
Acetilè
Àrees temàtiques de la UPC::Física
description Visualizing chemical reactions as they occur requires atomic spatial and femtosecond temporal resolution. Here, we report imaging of the molecular structure of acetylene (C2H2) 9 femtoseconds after ionization. Using mid-infrared laser–induced electron diffraction (LIED), we obtained snapshots as a proton departs the [C2H2]2+ ion. By introducing an additional laser field, we also demonstrate control over the ultrafast dissociation process and resolve different bond dynamics for molecules oriented parallel versus perpendicular to the LIED field. These measurements are in excellent agreement with a quantum chemical description of field-dressed molecular dynamics
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-10-16
2017
2017-06-28
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/105958
url https://hdl.handle.net/2117/105958
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://doi.org/10.13039/100010661 Horizon 2020 Framework Programme 654148 The Integrated Initiative of European Laser Research Infrastructures
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Science
publisher.none.fl_str_mv Science
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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