Magnetic properties of organic coated gold surfaces

We review here our recent results of experimental observation of room temperature magnetism in gold nanoparticles (NPs) and thin. films. Capping gold surfaces with certain organic molecules leads to the appearance of magnetism at room temperature. The surface bonds between the organic molecules and...

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Detalhes bibliográficos
Autores: De la Venta, J., Fernandez Pinel, E., García, M. A., Crespo del Arco, Patricia, Hernando Grande, Antonio, Rodríguez De La Fuente, Óscar, De Julián Fernández, C, Fernández, A, Penadés, S.
Formato: artículo
Fecha de publicación:2007
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/52006
Acesso em linha:https://hdl.handle.net/20.500.14352/52006
Access Level:acceso abierto
Palavra-chave:538.9
Cluster molecules
: Nanomagnetism
Surface magnetism
Nanoparticles
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descrição
Resumo:We review here our recent results of experimental observation of room temperature magnetism in gold nanoparticles (NPs) and thin. films. Capping gold surfaces with certain organic molecules leads to the appearance of magnetism at room temperature. The surface bonds between the organic molecules and Au atoms give rise to magnetic moments. These magnetic moments are blocked along the bond direction showing huge anisotropy. In the case of atomically. at surfaces, the magnetic moments are giants. An explanation of this orbital ferromagnetism is given. These results point out the possibility to observe magnetism at nanoscale in materials without typical magnetic atoms ( transition metals and rare earths), and are of fundamental value to understand the magnetic properties of surfaces.