Structure, Composition, Transport Properties, and Electrochemical Performance of the Electrode-Electrolyte Interphase in Non-Aqueous Na-Ion Batteries

[EN] Rechargeable Li-ion battery technology has progressed due to the development of a suitable combination of electroactive materials, binders, electrolytes, additives, and electrochemical cycling protocols that resulted in the formation of a stable electrode-electrolyte interphase. It is expected...

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Detalles Bibliográficos
Autores: Muñoz Márquez, Miguel Angel, Zarrabeitia Ipiña, Maider, Passerini, Stefano, Rojo Aparicio, Teófilo
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/56018
Acceso en línea:http://hdl.handle.net/10810/56018
Access Level:acceso abierto
Palabra clave:advanced electrolytes
interface models
liquid electrolytes
Na-ion batteries
solid electrolyte interphase
transport properties
X-ray photoelectron spectroscopy
Descripción
Sumario:[EN] Rechargeable Li-ion battery technology has progressed due to the development of a suitable combination of electroactive materials, binders, electrolytes, additives, and electrochemical cycling protocols that resulted in the formation of a stable electrode-electrolyte interphase. It is expected that Na-ion technology will attain a position comparable to Li-ion batteries dependent on advancements in establishing a stable electrode-electrolyte interphase. However, Li and Na are both alkali metals with similar characteristics, yet the physicochemical properties of these systems differ. For this reason, a detailed study on the electrode-electrolyte interphase properties, composition, and structure is required to understand the factors that influence the battery's behavior. Herein, the research that has been performed on the electrode-electrolyte interphase for both anode and cathode in the most important families of electrode materials, including carbonate ester-based and advanced electrolytes such as ether-based carbonates and ionic liquids is presented.