Influence of hydrogen bubbles adhering to the exposed surface on the corrosion rate of magnesium alloys AZ31 and AZ61 in sodium chloride solution

The influence of the presence of hydrogen bubbles adhered to the corroding specimen surface on the EIS estimations of corrosion rate of magnesium alloys is considered. The EIS corrosion rates for AZ31 specimens exposing a small area were four times higher than the real values determined by gravimetr...

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Detalles Bibliográficos
Autores: Feliú Jr., S., García Galván, Federico, Llorente, Irene, Díaz, Iván, Simancas Peco, Joaquín
Tipo de recurso: artículo
Estado:Versión enviada para evaluación y publicación
Fecha de publicación:2017
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/172325
Acceso en línea:http://hdl.handle.net/10261/172325
Access Level:acceso abierto
Palabra clave:Magnesium alloys
Weight loss
XPS
Passivity
EIS
Descripción
Sumario:The influence of the presence of hydrogen bubbles adhered to the corroding specimen surface on the EIS estimations of corrosion rate of magnesium alloys is considered. The EIS corrosion rates for AZ31 specimens exposing a small area were four times higher than the real values determined by gravimetric or hydrogen evolution measurements. In contrast, no significant differences in the corrosion rate have been observed in the case of the AZ61 specimens. A progressive deterioration in the protective properties of the corrosion products layer formed during the test was observed only on AZ31 specimens exposing a small area.