Photochemical water splitting via transition metal complexes

Photochemical water splitting by transition metal complexes provides a new approach to the production of hydrogen as a clean and sustainable energy carrier. Several selected systems are analyzed, and the two basic half reactions in the water splitting process which generates hydrogen and the compoun...

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Detalles Bibliográficos
Autores: Rosales Martínez, Antonio, Rodríguez-García, Ignacio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/159474
Acceso en línea:https://hdl.handle.net/11441/159474
https://doi.org/10.1016/j.jcat.2024.115415
Access Level:acceso abierto
Palabra clave:Water splitting
Titanocene
Transition metal complexes
Photochemical
Hydrogen
Descripción
Sumario:Photochemical water splitting by transition metal complexes provides a new approach to the production of hydrogen as a clean and sustainable energy carrier. Several selected systems are analyzed, and the two basic half reactions in the water splitting process which generates hydrogen and the compound of water oxidation (oxygen or hydrogen peroxide) are presented. Finally, a system designed for photochemical water splitting, based on the radical and organometallic chemistry of titanocene(III), is postulated.