Modification of surface wettability of sodium ionomer sheets via atmospheric plasma treatment

[EN] In this study, atmospheric plasma treatment has been used to modify the wetting properties of ethylene-methacrylic acid sodium ionomer. The effects of the plasma treatment on surface properties of this ionomer have been followed by contact angle measurements, Fourier transformed infrared spectr...

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Bibliographic Details
Authors: España Giner, José Manuel, Garcia-Sanoguera, David|||0000-0002-1923-9519, Sanchez-Nacher, Lourdes|||0000-0002-8627-4576, López-Martínez, Juan|||0000-0001-6904-2282, Balart, Rafael|||0000-0001-5670-7126
Format: article
Publication Date:2012
Country:España
Institution:Universitat Politècnica de València (UPV)
Repository:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Language:English
OAI Identifier:oai:riunet.upv.es:10251/35296
Online Access:https://riunet.upv.es/handle/10251/35296
Access Level:Open access
Keyword:Atmospheric plasma treatments
Fourier transformed infrared spectroscopy
FTIR
Plasma treatment
Processing parameters
Surface free energy
Surface wettability
Wetting property
Atomic force microscopy
Contact angle
Ethylene
Infrared spectroscopy
Plasma applications
Scanning electron microscopy
Sodium
Surface properties
Wetting
Plasma diagnostics
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
INGENIERIA MECANICA
Description
Summary:[EN] In this study, atmospheric plasma treatment has been used to modify the wetting properties of ethylene-methacrylic acid sodium ionomer. The effects of the plasma treatment on surface properties of this ionomer have been followed by contact angle measurements, Fourier transformed infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and atomic force microscopy (AFM). With the use of these techniques, the overall effects on activation-functionalization and surface topography changes have been determined in terms of the processing parameters of the atmospheric plasma treatment (rate and distance). The obtained results show a remarkable increase of the wetting properties and optimum balanced behavior is obtained for atmospheric plasma treatment with a rate of 100 mm/s and a distance of 6 mm; in this case, surface free energy is increased from 33 mJ/m2 (untreated ionomer) up to 62 mJ/m2, maintaining good transparency. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers Copyright © 2012 Society of Plastics Engineers.