Recent advances in silicon-based nanostructures for thermoelectric applications

In this work, implementations of silicon-based thermoelectric nanomaterials are reviewed. Approaches ranging from nanostructured bulk - i.e., macroscopic materials presenting nanoscale features - to more complex low-dimensional materials are covered. These implementations take advantage of different...

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Detalles Bibliográficos
Autores: Sojo Gordillo, Jose Manuel, Morata, Alex, Sierra, Carolina Duque, Salleras, Marc, Fonseca, Luis, Tarancón, Albert
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/347663
Acceso en línea:http://hdl.handle.net/10261/347663
https://api.elsevier.com/content/abstract/scopus_id/85153797797
Access Level:acceso abierto
Palabra clave:Films
Nanostructures
Silicon
Electronic band structure
Low-dimensional materials
Macroscopic materials
Nanoscale features
Nanostructured materials
Descripción
Sumario:In this work, implementations of silicon-based thermoelectric nanomaterials are reviewed. Approaches ranging from nanostructured bulk - i.e., macroscopic materials presenting nanoscale features - to more complex low-dimensional materials are covered. These implementations take advantage of different phonon scattering mechanisms and eventual modifications of the electronic band-structure for the enhancement of the thermoelectric figure of merit. This work is focused on the recent advances in silicon and silicon-based thermoelectric nanomaterials of the last decade - at both the theoretical and experimental level - with the spotlight on the most recent works. Different nanostructures and their fabrication methods are detailed, while the thermoelectric performances and the feasibility of their integration into functional micro-harvester generators are compared and discussed. This Research Update first covers the advances in nanostructured bulk, such as nanometric-sized polycrystals or defect-induced materials. Subsequently, it reviews low-dimensional materials, namely, thin films and nanowires. Later, other complex structures based on nanoporosity, superlattices, or core-shell schemes are detailed. Finally, it is devoted to present examples of the successful implementation of nanostructured silicon into functional thermoelectric devices.