Isomannide-containing poly(butylene 2,5-furandicarboxylate) copolyesters via ring opening polymerization
Cyclic oligomers of isomannide 2,5-furandicarboxylate were synthesized using the high dilution condensation method. A mixture of dimer, trimer, and tetramer species largely enriched in dimer was obtained. These cyclic oligomers were made to react with oligo(butylene 2,5-furandicarboxylate) in bulk a...
| Autores: | , , , |
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| Tipo de documento: | artigo |
| Data de publicação: | 2018 |
| País: | España |
| Recursos: | Universitat Politècnica de Catalunya (UPC) |
| Repositório: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglês |
| OAI Identifier: | oai:upcommons.upc.edu:2117/118550 |
| Acesso em linha: | https://hdl.handle.net/2117/118550 https://dx.doi.org/10.1021/acs.macromol.8b00487 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Oligomers Ring-opening polymerization Copolymers Polyesters Ring Opening Polymerization cyclic oligomers Isomanide FDCA copolyesters renewable resources. Oligòmers Copolímers Polièsters Polimerització Àrees temàtiques de la UPC::Enginyeria química |
| Resumo: | Cyclic oligomers of isomannide 2,5-furandicarboxylate were synthesized using the high dilution condensation method. A mixture of dimer, trimer, and tetramer species largely enriched in dimer was obtained. These cyclic oligomers were made to react with oligo(butylene 2,5-furandicarboxylate) in bulk at 220 °C by ring opening polymerization using Sn(Oct)2 as a catalyst. A series of random poly(butylene 2,5-furandicarboxylate) copolyesters containing isomannide in a range of 5–50 mol % and with weight-average molecular weights between 30,000 and 50,000 g·mol–1 were prepared. These copolyesters started to decompose above 300 °C, and only those containing less than 10 mol % of isomannide showed signs of crystallinity. They displayed glass-transition temperatures in the 40–100 °C range with values increasing steadily with the content in isomannide. At difference with poly(butylene 2,5-furandicarboxylate) homopolyester that is reluctant to undergo hydrolysis, the isomannide-containing copolyesters were noticeably degraded by water, much more rapidly when exposed to lipases. |
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