An improved synthesis of p-phenylene-bridged methylated binuclear ferrocene
This contribution describes an updated synthetic route along with full characterization of [{CpFe}2-p-Ph’] with p-Ph’: p-Bis{2,3,4,5tetramethylcyclopentadienyl}benzene). The complex reported here was characterized by 1H and 13C NMR, elemental analysis, the X-ray crystal structure, and Mössbauer spec...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/272680 |
| Acceso en línea: | http://hdl.handle.net/10261/272680 https://api.elsevier.com/content/abstract/scopus_id/85130210102 |
| Access Level: | acceso abierto |
| Palabra clave: | Ferrocene Homobimetallic compound Mössbauer spectroscopy X-ray |
| Sumario: | This contribution describes an updated synthetic route along with full characterization of [{CpFe}2-p-Ph’] with p-Ph’: p-Bis{2,3,4,5tetramethylcyclopentadienyl}benzene). The complex reported here was characterized by 1H and 13C NMR, elemental analysis, the X-ray crystal structure, and Mössbauer spectroscopy. From the crystallographic analysis, it was found that both {CpFe} fragments are coordinated to opposite sites of the p-Ph’ ligand. In addition, the analysis through of 1H and 13C NMR spectroscopy, confirm that the synthesis and yield of just one isomer of this compound. |
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