Nickel (0) complexes of polyunsaturated azamacrocyclic ligands

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic acti...

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Detalhes bibliográficos
Autores: Brun Massó, Sandra, Pla i Quintana, Anna, Roglans i Ribas, Anna, Pörschke, Klaus Richard, Goddard, Richard
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2012
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/11343
Acesso em linha:http://hdl.handle.net/10256/11343
Access Level:acceso embargado
Palavra-chave:Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
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spelling Nickel (0) complexes of polyunsaturated azamacrocyclic ligandsBrun Massó, SandraPla i Quintana, AnnaRoglans i Ribas, AnnaPörschke, Klaus RichardGoddard, RichardNíquel -- CompostosNickel compoundsMetalls de transició -- CompostosTransition metal compoundsA series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been testedThe project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grantAmerican Chemical Society (ACS)Ministerio de Ciencia e Innovación (Espanya)Ministerio de Educación y Ciencia (Espanya)Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recercainfoinfo2012info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10256/11343http://hdl.handle.net/10256/11343© Organometallics, 2012, vol. 31, núm. 5, p. 1983-1990Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1021/om201271yinfo:eu-repo/semantics/altIdentifier/issn/0276-7333info:eu-repo/semantics/altIdentifier/eissn/1520-6041info:eu-repo/grantAgreement/MICINN//CTQ2011-23121info:eu-repo/grantAgreement/MICINN//CTQ2008-05409-C02-02AGAUR/2009-2014/2009 SGR-637Tots els drets reservatsinfo:eu-repo/semantics/embargoedAccessoai:recercat.cat:10256/113432026-05-29T05:05:01Z
dc.title.none.fl_str_mv Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
title Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
spellingShingle Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
Brun Massó, Sandra
Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
title_short Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
title_full Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
title_fullStr Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
title_full_unstemmed Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
title_sort Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
dc.creator.none.fl_str_mv Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Pörschke, Klaus Richard
Goddard, Richard
author Brun Massó, Sandra
author_facet Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Pörschke, Klaus Richard
Goddard, Richard
author_role author
author2 Pla i Quintana, Anna
Roglans i Ribas, Anna
Pörschke, Klaus Richard
Goddard, Richard
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (Espanya)
Ministerio de Educación y Ciencia (Espanya)
Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca
dc.subject.none.fl_str_mv Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
topic Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
description A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested
publishDate 2012
dc.date.none.fl_str_mv 2012
info
info
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/11343
http://hdl.handle.net/10256/11343
url http://hdl.handle.net/10256/11343
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/om201271y
info:eu-repo/semantics/altIdentifier/issn/0276-7333
info:eu-repo/semantics/altIdentifier/eissn/1520-6041
info:eu-repo/grantAgreement/MICINN//CTQ2011-23121
info:eu-repo/grantAgreement/MICINN//CTQ2008-05409-C02-02
AGAUR/2009-2014/2009 SGR-637
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society (ACS)
publisher.none.fl_str_mv American Chemical Society (ACS)
dc.source.none.fl_str_mv © Organometallics, 2012, vol. 31, núm. 5, p. 1983-1990
Articles publicats (D-Q)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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