Multicomponent Reactions upon the Known Drug Trimethoprim as a Source of Novel Antimicrobial Agents

Novel antibiotic compounds have been prepared through a selective multicomponent reaction upon the known drug Trimethoprim. The Groebke-Blackburn-Bienaymé reaction involving this α-aminoazine, with a range of aldehydes and isocyanides afforded the desired adducts in one-step. The analogs display mea...

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Detalhes bibliográficos
Autores: Pedrola, Marina, Jorba, Marta, Jardas, Eda, Jardi, Ferran, Ghashghaei, Ouldouz, Viñas, Miquel, Lavilla Grífols, Rodolfo
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Recursos:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/165079
Acesso em linha:https://hdl.handle.net/2445/165079
Access Level:acceso abierto
Palavra-chave:Antibiòtics
Medicaments
Bacteris
Isonitrils
Antibiotics
Drugs
Bacteria
Isocyanides
Descrição
Resumo:Novel antibiotic compounds have been prepared through a selective multicomponent reaction upon the known drug Trimethoprim. The Groebke-Blackburn-Bienaymé reaction involving this α-aminoazine, with a range of aldehydes and isocyanides afforded the desired adducts in one-step. The analogs display meaningful structural features of the initial drug together with relevant modifications at several points, keeping antibiotic potency and showing satisfactory antimicrobial profile (good activity levels and reduced growth rates), especially against methicillin-resistant Staphylococcus aureus. The new products may open new possibilities to fight bacterial infections.