Alkyl and alkylidene imido cyclopentadienyl tungsten complexes

This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (Cp′=η5-C5H5, η5-C5Me5) with β-hydrogen containing alkyl groups to render halo alkyl and trialkyl complexes [WCp′(NtBu)Cl3−nRn] (R=Et, n-Pr). Thermal decomposition of the trialkyl compounds gives the a...

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Authors: Acebrón Moreno, Sergio, Galajov Garmize, Miguel, Gómez Sal, Pilar|||0000-0002-9279-210X, Martín Alonso, Avelino|||0000-0002-9776-9670, Royo Gracia, Pascual, Vázquez de Miguel, Amelio
Format: article
Publication Date:1999
Country:España
Institution:Universidad de Alcalá (UAH)
Repository:e_Buah Biblioteca Digital Universidad de Alcalá
Language:English
OAI Identifier:oai:ebuah.uah.es:10017/4243
Online Access:http://hdl.handle.net/10017/4243
https://dx.doi.org/10.1016/S0022-328X(98)01132-2
Access Level:Open access
Keyword:Alkyl
Alkylidene
Imido
Tungsten
Ciencia
Química inorgánica
Science
Chemistry, inorganic
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spelling Alkyl and alkylidene imido cyclopentadienyl tungsten complexesAcebrón Moreno, SergioGalajov Garmize, MiguelGómez Sal, Pilar|||0000-0002-9279-210XMartín Alonso, Avelino|||0000-0002-9776-9670Royo Gracia, PascualVázquez de Miguel, AmelioAlkylAlkylideneImidoTungstenCienciaQuímica inorgánicaScienceChemistry, inorganicThis paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (Cp′=η5-C5H5, η5-C5Me5) with β-hydrogen containing alkyl groups to render halo alkyl and trialkyl complexes [WCp′(NtBu)Cl3−nRn] (R=Et, n-Pr). Thermal decomposition of the trialkyl compounds gives the alkylidene derivatives [WCp′(NtBu)(CHR)(CH2R)] (R=Me, Et) by α-hydrogen elimination. All of the compounds were characterized by NMR spectroscopy and the molecular structure of [W(η5-C5Me5)(NtBu)Et3] was determined by X-ray diffraction methods.Dirección General de Investigación Científica y TécnicaElsevier19991999-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4243https://dx.doi.org/10.1016/S0022-328X(98)01132-2reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/42432026-06-18T11:13:07Z
dc.title.none.fl_str_mv Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
title Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
spellingShingle Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
Acebrón Moreno, Sergio
Alkyl
Alkylidene
Imido
Tungsten
Ciencia
Química inorgánica
Science
Chemistry, inorganic
title_short Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
title_full Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
title_fullStr Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
title_full_unstemmed Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
title_sort Alkyl and alkylidene imido cyclopentadienyl tungsten complexes
dc.creator.none.fl_str_mv Acebrón Moreno, Sergio
Galajov Garmize, Miguel
Gómez Sal, Pilar|||0000-0002-9279-210X
Martín Alonso, Avelino|||0000-0002-9776-9670
Royo Gracia, Pascual
Vázquez de Miguel, Amelio
author Acebrón Moreno, Sergio
author_facet Acebrón Moreno, Sergio
Galajov Garmize, Miguel
Gómez Sal, Pilar|||0000-0002-9279-210X
Martín Alonso, Avelino|||0000-0002-9776-9670
Royo Gracia, Pascual
Vázquez de Miguel, Amelio
author_role author
author2 Galajov Garmize, Miguel
Gómez Sal, Pilar|||0000-0002-9279-210X
Martín Alonso, Avelino|||0000-0002-9776-9670
Royo Gracia, Pascual
Vázquez de Miguel, Amelio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Alkyl
Alkylidene
Imido
Tungsten
Ciencia
Química inorgánica
Science
Chemistry, inorganic
topic Alkyl
Alkylidene
Imido
Tungsten
Ciencia
Química inorgánica
Science
Chemistry, inorganic
description This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (Cp′=η5-C5H5, η5-C5Me5) with β-hydrogen containing alkyl groups to render halo alkyl and trialkyl complexes [WCp′(NtBu)Cl3−nRn] (R=Et, n-Pr). Thermal decomposition of the trialkyl compounds gives the alkylidene derivatives [WCp′(NtBu)(CHR)(CH2R)] (R=Me, Et) by α-hydrogen elimination. All of the compounds were characterized by NMR spectroscopy and the molecular structure of [W(η5-C5Me5)(NtBu)Et3] was determined by X-ray diffraction methods.
publishDate 1999
dc.date.none.fl_str_mv 1999
1999-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/4243
https://dx.doi.org/10.1016/S0022-328X(98)01132-2
url http://hdl.handle.net/10017/4243
https://dx.doi.org/10.1016/S0022-328X(98)01132-2
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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