Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide

Global warming and related climate change urgently call for approaches to reduce carbon emissions and simultaneously reuse them as readily available carbon sources. Carbon dioxide (CO2) represents the most familiar one, and conversion of it into useful organic compounds can be both economically and...

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Detalles Bibliográficos
Autores: Kleij, Arjan W., Kilic, Ahmet, Aytar, Emine
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/482442
Acceso en línea:http://hdl.handle.net/2072/482442
https://doi.org/10.1002/cctc.202500002
Access Level:acceso abierto
Palabra clave:Química
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spelling Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon DioxideKleij, Arjan W.Kilic, AhmetAytar, EmineQuímica54Global warming and related climate change urgently call for approaches to reduce carbon emissions and simultaneously reuse them as readily available carbon sources. Carbon dioxide (CO2) represents the most familiar one, and conversion of it into useful organic compounds can be both economically and environmentally attractive. To enable these targets, new effective catalysis approaches are warranted allowing for once-captured CO2 to be transformed. In this context, the synthesis of organic carbonates is a primer example of a nonreductive approximation that has been well-studied and -developed over the last two decades. However, the search for alternative catalytic systems for the conversion of CO2 into organic carbonates still continues. The primary incentive involves the expansion of the chemical space covered by these compounds, their functionality and applications and the development of mild and environmentally more attractive catalytic processes. Boron-catalysis, being essentially metal-free, offers various advantages being affordable, amenable to design and presenting high-reactive alternatives for metal-based catalysts. This review covers the most important advances made with boron-catalysis in the area of organic carbonate synthesis focusing on their synthesis methods, mode of action and opportunities they provide to create new cyclic and polymeric carbonate structures.info:eu-repo/semantics/publishedVersionChemistry Europe2025info:eu-repo/semantics/article16 p.application/pdfhttp://hdl.handle.net/2072/482442https://doi.org/10.1002/cctc.202500002RECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésScientific and Technological Research Council of Turkey (TUBITAK) under grant number 221Z143Emine Aytar and Ahmet Kilic thank TUBITAK for its generous supportCERCA Program/Generalitat de CatalunyaICREAMinisterio de Ciencia e Innovación and the Ministerio de Ciencia, Innovación y Universidades (grants PID2020-112684GB-100, PID2023-149295NB-I00, and Severo Ochoa Excellence Accreditation 2020–2023 CEX2019-000925-S)AGAUR (2021-SGR-00853)Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2072/4824422026-05-29T05:05:01Z
dc.title.none.fl_str_mv Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
title Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
spellingShingle Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
Kleij, Arjan W.
Química
54
title_short Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
title_full Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
title_fullStr Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
title_full_unstemmed Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
title_sort Boron Catalysis to Expedite the Synthesis of Organic Carbonates from Carbon Dioxide
dc.creator.none.fl_str_mv Kleij, Arjan W.
Kilic, Ahmet
Aytar, Emine
author Kleij, Arjan W.
author_facet Kleij, Arjan W.
Kilic, Ahmet
Aytar, Emine
author_role author
author2 Kilic, Ahmet
Aytar, Emine
author2_role author
author
dc.subject.none.fl_str_mv Química
54
topic Química
54
description Global warming and related climate change urgently call for approaches to reduce carbon emissions and simultaneously reuse them as readily available carbon sources. Carbon dioxide (CO2) represents the most familiar one, and conversion of it into useful organic compounds can be both economically and environmentally attractive. To enable these targets, new effective catalysis approaches are warranted allowing for once-captured CO2 to be transformed. In this context, the synthesis of organic carbonates is a primer example of a nonreductive approximation that has been well-studied and -developed over the last two decades. However, the search for alternative catalytic systems for the conversion of CO2 into organic carbonates still continues. The primary incentive involves the expansion of the chemical space covered by these compounds, their functionality and applications and the development of mild and environmentally more attractive catalytic processes. Boron-catalysis, being essentially metal-free, offers various advantages being affordable, amenable to design and presenting high-reactive alternatives for metal-based catalysts. This review covers the most important advances made with boron-catalysis in the area of organic carbonate synthesis focusing on their synthesis methods, mode of action and opportunities they provide to create new cyclic and polymeric carbonate structures.
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/482442
https://doi.org/10.1002/cctc.202500002
url http://hdl.handle.net/2072/482442
https://doi.org/10.1002/cctc.202500002
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Scientific and Technological Research Council of Turkey (TUBITAK) under grant number 221Z143
Emine Aytar and Ahmet Kilic thank TUBITAK for its generous support
CERCA Program/Generalitat de Catalunya
ICREA
Ministerio de Ciencia e Innovación and the Ministerio de Ciencia, Innovación y Universidades (grants PID2020-112684GB-100, PID2023-149295NB-I00, and Severo Ochoa Excellence Accreditation 2020–2023 CEX2019-000925-S)
AGAUR (2021-SGR-00853)
dc.rights.none.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 16 p.
application/pdf
dc.publisher.none.fl_str_mv Chemistry Europe
publisher.none.fl_str_mv Chemistry Europe
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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