Fit-for-use nanofibrillated cellulose from recovered paper

The cost-effective implementation of nanofibrillated cellulose (CNF) at industrial scale requires optimizing the quality of the nanofibers according to their final application. Therefore, a portfolio of CNFs with different qualities is necessary, as well as further knowledge about how to obtain each...

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Detalles Bibliográficos
Autores: Balea Martín, Ana, Monte Lara, María Concepción, Fuente González, Elena de la, Sánchez Salvador, José Luis, Tarrés, Quim, Mutjé, Pere, Delgado-Aguilar, Marc, Negro Álvarez, Carlos Manuel
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/91110
Acceso en línea:https://hdl.handle.net/20.500.14352/91110
Access Level:acceso abierto
Palabra clave:66
Recycled fibers
Nanocellulose
Enzymatic pretreatments
TEMPO-mediated oxidation
Refining
High-pressure homogenization
Ingeniería química
Industria del papel
3303 Ingeniería y Tecnología Químicas
Descripción
Sumario:The cost-effective implementation of nanofibrillated cellulose (CNF) at industrial scale requires optimizing the quality of the nanofibers according to their final application. Therefore, a portfolio of CNFs with different qualities is necessary, as well as further knowledge about how to obtain each of the main qualities. This paper presents the influence of various production techniques on the morphological characteristics and properties of CNFs produced from a mixture of recycled fibers. Five different pretreatments have been investigated: a mechanical pretreatment (PFI refining), two enzymatic hydrolysis strategies, and TEMPO-mediated oxidation under two different NaClO concentrations. For each pretreatment, five high-pressure homogenization (HPH) conditions have been considered. Our results show that the pretreatment determines the yield and the potential of HPH to enhance fibrillation and, therefore, the final CNF properties. These results enable one to select the most effective production method with the highest yield of produced CNFs from recovered paper for the desired CNF quality in diverse applications.