Comparison of collection methods to determine atmospheric deposition in a rural Mediterranean site (NE Spain)

Wet-only, dry-only, bulk deposition and deposition of sedimentary particles and gases deposited after the last rain (DAR) were collected weekly at La Castanya station in the Montseny mountains (NE Spain, 41°46'N, 2°21'E) from February 2009 to July 2010. These samples were analysed for pH,...

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Detalles Bibliográficos
Autores: Izquierdo Miguel, Rebeca|||0000-0001-5780-4462, Àvila i Castells, Anna|||0000-0002-4137-0839
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:148107
Acceso en línea:https://ddd.uab.cat/record/148107
https://dx.doi.org/urn:doi:10.1007/s10874-012-9246-1
Access Level:acceso abierto
Palabra clave:Atmospheric input
Bulk deposition
Dry deposition
Mediterranean region
Precipitation chemistry
Wet deposition
Descripción
Sumario:Wet-only, dry-only, bulk deposition and deposition of sedimentary particles and gases deposited after the last rain (DAR) were collected weekly at La Castanya station in the Montseny mountains (NE Spain, 41°46'N, 2°21'E) from February 2009 to July 2010. These samples were analysed for pH, alkalinity, and the concentrations of major ions (Cl⁻, NO₃⁻, SO₄²⁻, Na⁺, K⁺, Ca²⁺, Mg²⁺, NH₄⁺). Significant differences were observed between bulk and wet-only precipitation, with an enrichment of ions associated to coarse particles in bulk deposition. The comparison between wet and dry fluxes revealed that the removal of compounds at Montseny occurred mainly by wet deposition, which accounted for 74 % of total deposition. The dry flux was characterised by the predominance of K⁺ , Ca²⁺ and Mg²⁺, which are related to coarse particles. Bulk collection methods at Montseny were considered representative of total atmospheric deposition, since bulk deposition plus DAR accounted for 97 % of total deposition measured with wet and dry-only collection devices. Thus, bulk deposition collectors can be recommended for deposition networks at remote sites (lacking electricity connection) in environments, where coarse particles are a predominant fraction of the aerosol mass.