Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars
The data used in this publication include rock target close up images (WATSON, Figures 1-6, 1014 NASA PDS https://doi.org/10.17189/1522643, Beegle et al., 2021) X-ray fluorescence data 1015 (PIXL, Figures 2-6; Table 1, Figure S1 in Supporting Information S1 and Table S2, Tables S3 and S4 in Supporti...
| Autores: | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/388081 |
| Acceso en línea: | http://hdl.handle.net/10261/388081 https://api.elsevier.com/content/abstract/scopus_id/85182815554 |
| Access Level: | acceso abierto |
| Palabra clave: | Hydration Mars Perseverance PIXL SHERLOC Sulfate |
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Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| title |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| spellingShingle |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars Siljeström, Sandra Hydration Mars Perseverance PIXL SHERLOC Sulfate |
| title_short |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| title_full |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| title_fullStr |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| title_full_unstemmed |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| title_sort |
Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, Mars |
| dc.creator.none.fl_str_mv |
Siljeström, Sandra Czaja, Andrew D. Corpolongo, Andrea Berger, Eve L. Li, An Y. Cardarelli, Emily Abbey, William Asher, Sanford A. Beegle, Luther W. Benison, Kathleen C. Bhartia, Rohit Bleefeld, Benjamin L. Burton, Aaron S. Bykov, Sergei V. Clark, Benton DeFlores, Lauren Ehlmann, Bethany L. Fornaro, Teresa Fox, Allie Gómez, Felipe Hand, Kevin Haney, Nikole C. Hickman-Lewis, Keyron Hug, William F. Imbeah, Samara Jakubek, Ryan S. Kah, Linda C. Kivrak, Lydia Lee, Carina Liu, Yang Martínez-Frías, Jesús McCubbin, Francis M. Minitti, Michelle Moore, Kelsey Morris, Richard V. Núñez, Jorge I. Osterhout, Jeffrey T. Phua, Yu Yu Randazzo, Nicolas Hollis, Joseph Razzell Rodriguez, Carolina Roppel, Ryan Scheller, Eva L. Sephton, Mark Sharma, Shiv K. Sharma, Sunanda Steadman, Kim Steele, Andrew Tice, Michael Uckert, Kyle VanBommel, Scott Williams, Amy J. Williford, Kenneth H. Winchell, Katherine Wu, Megan Kennedy Yanchilina, Anastasia Zorzano, Maria Paz |
| author |
Siljeström, Sandra |
| author_facet |
Siljeström, Sandra Czaja, Andrew D. Corpolongo, Andrea Berger, Eve L. Li, An Y. Cardarelli, Emily Abbey, William Asher, Sanford A. Beegle, Luther W. Benison, Kathleen C. Bhartia, Rohit Bleefeld, Benjamin L. Burton, Aaron S. Bykov, Sergei V. Clark, Benton DeFlores, Lauren Ehlmann, Bethany L. Fornaro, Teresa Fox, Allie Gómez, Felipe Hand, Kevin Haney, Nikole C. Hickman-Lewis, Keyron Hug, William F. Imbeah, Samara Jakubek, Ryan S. Kah, Linda C. Kivrak, Lydia Lee, Carina Liu, Yang Martínez-Frías, Jesús McCubbin, Francis M. Minitti, Michelle Moore, Kelsey Morris, Richard V. Núñez, Jorge I. Osterhout, Jeffrey T. Phua, Yu Yu Randazzo, Nicolas Hollis, Joseph Razzell Rodriguez, Carolina Roppel, Ryan Scheller, Eva L. Sephton, Mark Sharma, Shiv K. Sharma, Sunanda Steadman, Kim Steele, Andrew Tice, Michael Uckert, Kyle VanBommel, Scott Williams, Amy J. Williford, Kenneth H. Winchell, Katherine Wu, Megan Kennedy Yanchilina, Anastasia Zorzano, Maria Paz |
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author |
| author2 |
Czaja, Andrew D. Corpolongo, Andrea Berger, Eve L. Li, An Y. Cardarelli, Emily Abbey, William Asher, Sanford A. Beegle, Luther W. Benison, Kathleen C. Bhartia, Rohit Bleefeld, Benjamin L. Burton, Aaron S. Bykov, Sergei V. Clark, Benton DeFlores, Lauren Ehlmann, Bethany L. Fornaro, Teresa Fox, Allie Gómez, Felipe Hand, Kevin Haney, Nikole C. Hickman-Lewis, Keyron Hug, William F. Imbeah, Samara Jakubek, Ryan S. Kah, Linda C. Kivrak, Lydia Lee, Carina Liu, Yang Martínez-Frías, Jesús McCubbin, Francis M. Minitti, Michelle Moore, Kelsey Morris, Richard V. Núñez, Jorge I. Osterhout, Jeffrey T. Phua, Yu Yu Randazzo, Nicolas Hollis, Joseph Razzell Rodriguez, Carolina Roppel, Ryan Scheller, Eva L. Sephton, Mark Sharma, Shiv K. Sharma, Sunanda Steadman, Kim Steele, Andrew Tice, Michael Uckert, Kyle VanBommel, Scott Williams, Amy J. Williford, Kenneth H. Winchell, Katherine Wu, Megan Kennedy Yanchilina, Anastasia Zorzano, Maria Paz |
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author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author author |
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Swedish National Space Agency NASA UK Space Agency Ministerio de Ciencia e Innovación (España) Siljeström, Sandra [0000-0002-4975-6074] Czaja, Andrew D. [0000-0002-2450-0734] Corpolongo, Andrea [0000-0002-8623-358X] Cardarelli, Emily [0000-0001-5451-2309] Abbey, William [0000-0002-0555-6599] Benison, Kathleen C. [0000-0001-6104-2333] Bhartia, Rohit [0000-0002-1434-7481] Burton, Aaron S. [0000-0002-7137-1605]] Bykov, Sergei V. [0000-0002-6161-0027] Clark, Benton [0000-0002-5546-8757] Ehlmann, Bethany L. [0000-0002-2745-3240] Fornaro, Teresa [0000-0001-7705-9658] Fox, Allie [0000-0002-5952-4170] Gómez, Felipe [0000-0001-9977-7060] Hand, Kevin [0000-0002-3225-9426] Haney, Nikole C. [0000-0001-5405-3616] Kah, Linda C. [0000-0001-7172-2033] Liu, Yang [0000-0003-0308-0942] Martínez-Frías, Jesús [0000-0002-2609-4485] McCubbin, Francis M. [0000-0002-2101-4431] Minitti, Michelle [0000-0003-4715-4544] Morris, Richard V. [0000-0003-1413-4002] Núñez, Jorge I. [0000-0003-0930-6674] Phua, Yu Yu [0000-0001-9660-1991] Rodriguez, Carolina [0000-0002-0390-5054] Roppel, Ryan [0000-0002-1782-1388] Sephton, Mark [0000-0002-2190-5402] Sharma, Shiv K. [0000-0002-5676-7572] Steadman, Kim [0000-0002-3192-0489] Uckert, Kyle [0000-0002-0859-5526] Williams, Amy J. [0000-0001-6299-0845] Yanchilina, Anastasia [0000-0003-3782-6343] Zorzano, Maria Paz [0000-0002-4492-9650] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Hydration Mars Perseverance PIXL SHERLOC Sulfate |
| topic |
Hydration Mars Perseverance PIXL SHERLOC Sulfate |
| description |
The data used in this publication include rock target close up images (WATSON, Figures 1-6, 1014 NASA PDS https://doi.org/10.17189/1522643, Beegle et al., 2021) X-ray fluorescence data 1015 (PIXL, Figures 2-6; Table 1, Figure S1 in Supporting Information S1 and Table S2, Tables S3 and S4 in Supporting Information S1, NASA PDS 1016 https://doi.org/10.17189/1522645, Allwood & Hurowitz, 2021), Raman and fluorescence data 1017 (SHERLOC, Figures 2-8, Tables 2–3, and Table S1 in Supporting Information S1 and Table S5, NASA 1018 PDS https://doi.org/10.17189/1522643, Beegle et al., 2021), and atmospheric data (MEDA, 1019 NASA PDS https://doi.org/10.17189/1522849, Rodriguez-Manfredi et al., 2021). 1020 Software packages used in this publication for SHERLOC data include Loupe (version v.5.1.5, 1021 Uckert, 2022, Zenodo https://doi.org/10.5281/zenodo.7062998) and peak fitting program Fityk 1022 (version v.1.3.1; Wojdyr, 2010, https://fityk.nieto.pl/). 48 1023 PIQUANT (Version v3.2.11, Elam & Heirwegh, 2022, Zenodo: 1024 https://doi.org/10.5281/zenodo.6959125.), PIXLISE Core (Version v.2.0, Nemere et al., 2022a, 1025 Zenodo https://doi.org/10.5281/zenodo.6959096) and PIXLISE UI (Version v.2.0, Nemere et al., 2022b, 1026 Zenodo https://doi.org/10.5281/zenodo.6959109) were used to treat PIXL data. |
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2024 |
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2024 2025 2025 |
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info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
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article |
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publishedVersion |
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http://hdl.handle.net/10261/388081 https://api.elsevier.com/content/abstract/scopus_id/85182815554 |
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http://hdl.handle.net/10261/388081 https://api.elsevier.com/content/abstract/scopus_id/85182815554 |
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Inglés |
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#PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104205GB-C21 The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.1029/2023JE007989 https://doi.org/10.1029/2023JE007989 Sí |
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application/pdf |
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John Wiley & Sons |
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John Wiley & Sons |
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Evidence of Sulfate-Rich Fluid Alteration in Jezero Crater Floor, MarsSiljeström, SandraCzaja, Andrew D.Corpolongo, AndreaBerger, Eve L.Li, An Y.Cardarelli, EmilyAbbey, WilliamAsher, Sanford A.Beegle, Luther W.Benison, Kathleen C.Bhartia, RohitBleefeld, Benjamin L.Burton, Aaron S.Bykov, Sergei V.Clark, BentonDeFlores, LaurenEhlmann, Bethany L.Fornaro, TeresaFox, AllieGómez, FelipeHand, KevinHaney, Nikole C.Hickman-Lewis, KeyronHug, William F.Imbeah, SamaraJakubek, Ryan S.Kah, Linda C.Kivrak, LydiaLee, CarinaLiu, YangMartínez-Frías, JesúsMcCubbin, Francis M.Minitti, MichelleMoore, KelseyMorris, Richard V.Núñez, Jorge I.Osterhout, Jeffrey T.Phua, Yu YuRandazzo, NicolasHollis, Joseph RazzellRodriguez, CarolinaRoppel, RyanScheller, Eva L.Sephton, MarkSharma, Shiv K.Sharma, SunandaSteadman, KimSteele, AndrewTice, MichaelUckert, KyleVanBommel, ScottWilliams, Amy J.Williford, Kenneth H.Winchell, KatherineWu, Megan KennedyYanchilina, AnastasiaZorzano, Maria PazHydrationMarsPerseverancePIXLSHERLOCSulfateThe data used in this publication include rock target close up images (WATSON, Figures 1-6, 1014 NASA PDS https://doi.org/10.17189/1522643, Beegle et al., 2021) X-ray fluorescence data 1015 (PIXL, Figures 2-6; Table 1, Figure S1 in Supporting Information S1 and Table S2, Tables S3 and S4 in Supporting Information S1, NASA PDS 1016 https://doi.org/10.17189/1522645, Allwood & Hurowitz, 2021), Raman and fluorescence data 1017 (SHERLOC, Figures 2-8, Tables 2–3, and Table S1 in Supporting Information S1 and Table S5, NASA 1018 PDS https://doi.org/10.17189/1522643, Beegle et al., 2021), and atmospheric data (MEDA, 1019 NASA PDS https://doi.org/10.17189/1522849, Rodriguez-Manfredi et al., 2021). 1020 Software packages used in this publication for SHERLOC data include Loupe (version v.5.1.5, 1021 Uckert, 2022, Zenodo https://doi.org/10.5281/zenodo.7062998) and peak fitting program Fityk 1022 (version v.1.3.1; Wojdyr, 2010, https://fityk.nieto.pl/). 48 1023 PIQUANT (Version v3.2.11, Elam & Heirwegh, 2022, Zenodo: 1024 https://doi.org/10.5281/zenodo.6959125.), PIXLISE Core (Version v.2.0, Nemere et al., 2022a, 1025 Zenodo https://doi.org/10.5281/zenodo.6959096) and PIXLISE UI (Version v.2.0, Nemere et al., 2022b, 1026 Zenodo https://doi.org/10.5281/zenodo.6959109) were used to treat PIXL data.Sulfur plays a major role in martian geochemistry and sulfate minerals are important repositories of water. However, their hydration states on Mars are poorly constrained. Therefore, understanding the hydration and distribution of sulfate minerals on Mars is important for understanding its geologic, hydrologic, and atmospheric evolution as well as its habitability potential. NASA's Perseverance rover is currently exploring the Noachian-age Jezero crater, which hosts a fan-delta system associated with a paleolake. The crater floor includes two igneous units (the Séítah and Máaz formations), both of which contain evidence of later alteration by fluids including sulfate minerals. Results from the rover instruments Scanning Habitable Environments with Raman and Luminescence for Organics and Chemistry and Planetary Instrument for X-ray Lithochemistry reveal the presence of a mix of crystalline and amorphous hydrated Mg-sulfate minerals (both MgSO4·[3–5]H2O and possible MgSO4·H2O), and anhydrous Ca-sulfate minerals. The sulfate phases within each outcrop may have formed from single or multiple episodes of water activity, although several depositional events seem likely for the different units in the crater floor. Textural and chemical evidence suggest that the sulfate minerals most likely precipitated from a low temperature sulfate-rich fluid of moderate pH. The identification of approximately four waters puts a lower constraint on the hydration state of sulfate minerals in the shallow subsurface, which has implications for the martian hydrological budget. These sulfate minerals are key samples for future Mars sample return.We would like to thank the Mars 2020 Perseverance Science and Engineering teams for their work on the mission that has enabled the analysis of the crater floor targets. We also thank two anonymous reviewers who provided substantive feedback on a previous version of this paper. The work described in this paper was partially carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration. S.S. acknowledges funding from the Swedish National Space Agency (contracts 2021-00092 and 137/19). A.D.C. and A.C. were supported by the Mars 2020 Returned Sample Science Participating Scientist Program (NASA award number 80NSSC20K0237), and A.C was additionally supported by a National Science Foundation Graduate Research Fellowship (award number 2035701). AYL was supported by subcontract number 1655697 from JPL (from NASA as part of the Mars 2020 Phase E funding). BLE and YP were supported by NASA Mars 2020 Co-Investigator funds to support BLE on SHERLOC. KCB was supported by the Mars 2020 Returned Sample Science Participating Scientist Program (NASA award number 80NSSC20K0235). ASB was supported by the Mars 2020 Mission. TF was supported by the ASI/INAF agreement 2023-3-HH.0. NCH was supported by the JETS II contract with Johnson Space Center, NASA. KHL was supported by the UK Space Agency Aurora Research Fellowship (ST/V00560X/1). RSJ acknowledges funding from an Advanced Curation project run by the NASA Astromaterials Acquisition and Curation Office, Johnson Space Center. RVM was supported by the ISFM Mission Enabling Work Package at the Johnson Space Center. MM was supported by a contract with NASA/JPL (1685477). MAS was supported by UK Space Agency Grants ST/V002732/1 and ST/V006134/1. SKS acknowledges Mars 2020 SuperCam Co-PI support and contract with NASA/ JPL (1654163). SVB was supported by the Mars 2020 Participating Science Program, Grant 80NSSC21K0328. AJW was supported by the NASA Mars 2020 Participating Scientist Program, Grant 80NSSC21K0332. AY was supported by a contract with NASA/JPL (1651660). MPZ was supported by Grant PID2019- 104205GB-C21 funded by MCIN/ AEI/10.13039/501100011033.Peer reviewedJohn Wiley & SonsSwedish National Space AgencyNASAUK Space AgencyMinisterio de Ciencia e Innovación (España)Siljeström, Sandra [0000-0002-4975-6074]Czaja, Andrew D. [0000-0002-2450-0734]Corpolongo, Andrea [0000-0002-8623-358X]Cardarelli, Emily [0000-0001-5451-2309]Abbey, William [0000-0002-0555-6599]Benison, Kathleen C. [0000-0001-6104-2333]Bhartia, Rohit [0000-0002-1434-7481]Burton, Aaron S. [0000-0002-7137-1605]]Bykov, Sergei V. [0000-0002-6161-0027]Clark, Benton [0000-0002-5546-8757]Ehlmann, Bethany L. [0000-0002-2745-3240]Fornaro, Teresa [0000-0001-7705-9658]Fox, Allie [0000-0002-5952-4170]Gómez, Felipe [0000-0001-9977-7060]Hand, Kevin [0000-0002-3225-9426]Haney, Nikole C. [0000-0001-5405-3616]Kah, Linda C. [0000-0001-7172-2033]Liu, Yang [0000-0003-0308-0942]Martínez-Frías, Jesús [0000-0002-2609-4485]McCubbin, Francis M. [0000-0002-2101-4431]Minitti, Michelle [0000-0003-4715-4544]Morris, Richard V. [0000-0003-1413-4002]Núñez, Jorge I. [0000-0003-0930-6674]Phua, Yu Yu [0000-0001-9660-1991]Rodriguez, Carolina [0000-0002-0390-5054]Roppel, Ryan [0000-0002-1782-1388]Sephton, Mark [0000-0002-2190-5402]Sharma, Shiv K. [0000-0002-5676-7572]Steadman, Kim [0000-0002-3192-0489]Uckert, Kyle [0000-0002-0859-5526]Williams, Amy J. [0000-0001-6299-0845]Yanchilina, Anastasia [0000-0003-3782-6343]Zorzano, Maria Paz [0000-0002-4492-9650]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/388081https://api.elsevier.com/content/abstract/scopus_id/85182815554reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104205GB-C21The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI https://doi.org/10.1029/2023JE007989https://doi.org/10.1029/2023JE007989Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3880812026-05-22T06:33:51Z |
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