External sulfate attack in dam concretes with thaumasite formation

Concrete core samples extracted from different areas of the Mequinenza Dam (Spain) have been studied and expansive reactions affecting the structure were not found. However, expansive reactions in the concrete of certain parts located near the abutments of two galleries have been observed as a conse...

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Detalles Bibliográficos
Autores: Chinchón Payá, S., Aguado de Cea, Antonio|||0000-0001-5542-6365, Nugteren, H. W, Chinchón Yepes, Jose Servando
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/27227
Acceso en línea:https://hdl.handle.net/2117/27227
https://dx.doi.org/10.3989/mc.2015.10513
Access Level:acceso abierto
Palabra clave:Thaumasite
Concrete dams
Mequinenza (Spain)
Concrete dam
Sulfate attack
DELAYED ETTRINGITE FORMATION
GYPSUM FORMATION
CEMENT MORTARS
IRON SULFIDES
DETERIORATION
PERFORMANCE
OXIDATION
SYSTEM
MODEL
Sulfats
Preses de formigó
Mequinensa (Catalunya : Pantà)
Àrees temàtiques de la UPC::Enginyeria civil::Materials i estructures::Materials i estructures de formigó
Descripción
Sumario:Concrete core samples extracted from different areas of the Mequinenza Dam (Spain) have been studied and expansive reactions affecting the structure were not found. However, expansive reactions in the concrete of certain parts located near the abutments of two galleries have been observed as a consequence of an external sulfate attack due to the sulfur compounds contained in the lignites that are present on the surrounding terrain. Secondary gypsum, ettringite, and thaumasite, as well as several sulfate efflorescence have been detected. The thaumasite formed in the degraded concrete is related to a Thaumasite Sulfate Attack (TSA). Scanning Electron Microscopy (SEM) and Rietveld analyses of the TSA samples would show that thaumasite could have been formed thanks to ettringite acting as nuclei or by a direct precipitation from solutions within the pores of the cement matrix.