Dispersion-free extraction of In(III) from HCl solutions using a supported liquid membrane containing the HA324H+Cl− ionic liquid as the carrier

By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324HCl was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables affecting the permeation of indium(III) ac...

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Detalles Bibliográficos
Autores: Alguacil, Francisco José, López Gómez, Félix Antonio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/220935
Acceso en línea:http://hdl.handle.net/10261/220935
Access Level:acceso abierto
Palabra clave:Ionic liquid
HCl solutions
Membrane
Descripción
Sumario:By reaction of HCl and the tertiary amine HA324, an ionic liquid denoted HA324HCl was generated and used in the transport of indium(III) from HCl solutions. Metal transport experiments were carried out with a supported liquid membrane, and several variables affecting the permeation of indium(III) across the membrane were tested: stirring speed, metal and acid concentrations in the feed solutions and the carrier concentration in the supported organic solution. The metal transport results were also compared with those obtained using different carriers in the solid support. A model that described indium(III) transport across the was proposed, and the corresponding diffusional parameters were estimated.