Impact of Silver on the Structural and Wettability Properties of ZnO Films Grown by Oblique Angle Magnetron Sputtering

Un-doped (uZO) and silver-doped zinc oxide (SZO) films were prepared by oblique incidence sputtering deposition under different process parameters. The crystalline structure, chemical composition, and surface morphology were correlated with the optical properties, as well as with the wettability of...

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Detalhes bibliográficos
Autores: Álvarez-Fraga, Leo, Gago, Raúl, Araiza, José de Jesús, Azpeitia-Urkia, Jon, Jiménez, Ignacio, Sánchez Garrido, Olga
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2023
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/310513
Acesso em linha:http://hdl.handle.net/10261/310513
Access Level:Acceso aberto
Palavra-chave:Oblique angle deposition (OAD) sputtering
Silver doped ZnO
wurtzite-ZnO
Crystalline structure
Wettability
Contact angle
Descrição
Resumo:Un-doped (uZO) and silver-doped zinc oxide (SZO) films were prepared by oblique incidence sputtering deposition under different process parameters. The crystalline structure, chemical composition, and surface morphology were correlated with the optical properties, as well as with the wettability of the films. In the case of uZO films, the orientation, inclination, and morphology of the columnar structure determined the wettability of the layer, moving from a hydrophilic- to hydrophobic-like character. In the case of SZO films, although almost all of them displayed hydrophobic behavior, the hydrophobic character increased with the Ag content. The most hydrophobic surface was obtained when the Ag content in the layers was greater than 7 at.% and, in these cases, the structural results indicate that the layers were formed by a disordered mixture of Zn and Ag oxides.