Conformal oxide nanocoatings on electrodeposited 3D porous Ni films by atomic layer deposition

A versatile chemical synthesis procedure to obtain Al2O3 and Co2FeO4 nanolayers conformally coating a three-dimensional (3D) porous Ni film is presented. First, porous Ni is grown by hydrogen bubble template-assisted electrodeposition. Subsequently, Al2O3 and Co2FeO4 layers, with thickness ranging f...

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Bibliographic Details
Authors: Zhang, Jin, Coll, Maria Dolors, Puig i Molina, Mª Teresa|||0000-0002-1873-0488, Pellicer, Eva|||0000-0002-8901-0998, Sort, Jordi|||0000-0003-1213-3639
Format: article
Publication Date:2016
Country:España
Institution:Universitat Autònoma de Barcelona
Repository:Dipòsit Digital de Documents de la UAB
Language:English
OAI Identifier:oai:ddd.uab.cat:170448
Online Access:https://ddd.uab.cat/record/170448
https://dx.doi.org/urn:doi:10.1039/c6tc02656g
Access Level:Open access
Description
Summary:A versatile chemical synthesis procedure to obtain Al2O3 and Co2FeO4 nanolayers conformally coating a three-dimensional (3D) porous Ni film is presented. First, porous Ni is grown by hydrogen bubble template-assisted electrodeposition. Subsequently, Al2O3 and Co2FeO4 layers, with thickness ranging from 5 nm to 25 nm, are directly deposited onto the pore walls by atomic layer deposition, while maintaining the porous architecture and magnetic properties of the Ni scaffold. The crystal structure, thickness and distribution of elements within the composite coatings are investigated in detail. The resulting magnetic and wettability properties are assessed. Contact angle tests reveal that 3D porous Ni films become more hydrophilic after coating with Al2O3 or Co2FeO4. From a technological point of view, the obtained composite porous films could be appealing for applications like magnetically-actuated micro/nano-electromechanical systems (MEMS/NEMS) or bio-MEMS/NEMS, among others.