Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite
A fragment of the NWA 2975 Martian meteorite, an enriched basaltic shergottite, was analysed to complete its geochemical characterisation performed 10 years ago. By this means, the feasibility of the employed techniques in a combined way for present and future space exploration missions can be teste...
| Autores: | , , , , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/92373 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/92373 |
| Access Level: | acceso abierto |
| Palabra clave: | 543.426 543.422.2 543.42 523.68 LIBS micro-Raman spectroscopy NWA 2975 Martian shergottite weathering μ-EDXRF Óptica (Física) Física de materiales 2209.19 Óptica Física 2209.21 Espectroscopia 2104.02 Meteoritos |
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Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottitePoblación, IratxeTorre Fernández, ImanolAramendia, JuleneLópez Reyes, GuillermoCabalín, Luisa M.Madariaga, Juan ManuelRull, FernandoLaserna, Javier J.Carrizo, DanielMartínez Frías , JesúsBelenguer, TomásBelenguer Dávila, TomásTaravillo Corralo, MercedesDell'Agliom, MaecellaDe Giacomo, AlessandroHuidobro, JenniferManrique, Jose AntonioDelgado, TomásArana, GorkaCastro, KepaVeneranda, MarcoSanz Arranz, J.A.Fortes, F.JavierGarcía Gómez, Laura543.426543.422.2543.42523.68LIBSmicro-Raman spectroscopyNWA 2975 Martian shergottiteweatheringμ-EDXRFÓptica (Física)Física de materiales2209.19 Óptica Física2209.21 Espectroscopia2104.02 MeteoritosA fragment of the NWA 2975 Martian meteorite, an enriched basaltic shergottite, was analysed to complete its geochemical characterisation performed 10 years ago. By this means, the feasibility of the employed techniques in a combined way for present and future space exploration missions can be tested. For this aim, Raman spectroscopy was used supported by micro energy dispersive X-ray fluorescence (μ-EDXRF) and laser-induced breakdown spectroscopy (LIBS) for an accurate interpretation of molecular and elemental results. Raman spectroscopy results from two setups, InVia from Renishaw and RLS Simulator, were compared. The major minerals detected by Raman spectroscopy were pyroxenes (mainly augite, pigeonite and enstatite) and plagioclases (mainly shocked maskelynite). Raman spectroscopy allowed defining different metal compositions for these main minerals based on the secondary Raman spectroscopy bands in the 200–500 cm−1 region. In addition, other minerals were found such as merrillite, as well as pyrrhotite and apatite, in several veins and cracks of the meteorite, in agreement with the initial report by the Meteoritical Bulletin. Moreover, it should be highlighted that coesite was found for the very first time in this meteorite.WileyUniversidad Complutense de Madrid20232023-01-0120232023-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/92373reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/923732026-06-02T12:44:21Z |
| dc.title.none.fl_str_mv |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| title |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| spellingShingle |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite Población, Iratxe 543.426 543.422.2 543.42 523.68 LIBS micro-Raman spectroscopy NWA 2975 Martian shergottite weathering μ-EDXRF Óptica (Física) Física de materiales 2209.19 Óptica Física 2209.21 Espectroscopia 2104.02 Meteoritos |
| title_short |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| title_full |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| title_fullStr |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| title_full_unstemmed |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| title_sort |
Raman spectroscopy, assisted by X-ray fluorescence and laser-induced breakdown spectroscopy, to characterise original and altered mineral phases in the NWA 2975 Martian shergottite |
| dc.creator.none.fl_str_mv |
Población, Iratxe Torre Fernández, Imanol Aramendia, Julene López Reyes, Guillermo Cabalín, Luisa M. Madariaga, Juan Manuel Rull, Fernando Laserna, Javier J. Carrizo, Daniel Martínez Frías , Jesús Belenguer, Tomás Belenguer Dávila, Tomás Taravillo Corralo, Mercedes Dell'Agliom, Maecella De Giacomo, Alessandro Huidobro, Jennifer Manrique, Jose Antonio Delgado, Tomás Arana, Gorka Castro, Kepa Veneranda, Marco Sanz Arranz, J.A. Fortes, F.Javier García Gómez, Laura |
| author |
Población, Iratxe |
| author_facet |
Población, Iratxe Torre Fernández, Imanol Aramendia, Julene López Reyes, Guillermo Cabalín, Luisa M. Madariaga, Juan Manuel Rull, Fernando Laserna, Javier J. Carrizo, Daniel Martínez Frías , Jesús Belenguer, Tomás Belenguer Dávila, Tomás Taravillo Corralo, Mercedes Dell'Agliom, Maecella De Giacomo, Alessandro Huidobro, Jennifer Manrique, Jose Antonio Delgado, Tomás Arana, Gorka Castro, Kepa Veneranda, Marco Sanz Arranz, J.A. Fortes, F.Javier García Gómez, Laura |
| author_role |
author |
| author2 |
Torre Fernández, Imanol Aramendia, Julene López Reyes, Guillermo Cabalín, Luisa M. Madariaga, Juan Manuel Rull, Fernando Laserna, Javier J. Carrizo, Daniel Martínez Frías , Jesús Belenguer, Tomás Belenguer Dávila, Tomás Taravillo Corralo, Mercedes Dell'Agliom, Maecella De Giacomo, Alessandro Huidobro, Jennifer Manrique, Jose Antonio Delgado, Tomás Arana, Gorka Castro, Kepa Veneranda, Marco Sanz Arranz, J.A. Fortes, F.Javier García Gómez, Laura |
| author2_role |
author author author author author author author author author author author author author author author author author author author author author author author |
| dc.contributor.none.fl_str_mv |
Universidad Complutense de Madrid |
| dc.subject.none.fl_str_mv |
543.426 543.422.2 543.42 523.68 LIBS micro-Raman spectroscopy NWA 2975 Martian shergottite weathering μ-EDXRF Óptica (Física) Física de materiales 2209.19 Óptica Física 2209.21 Espectroscopia 2104.02 Meteoritos |
| topic |
543.426 543.422.2 543.42 523.68 LIBS micro-Raman spectroscopy NWA 2975 Martian shergottite weathering μ-EDXRF Óptica (Física) Física de materiales 2209.19 Óptica Física 2209.21 Espectroscopia 2104.02 Meteoritos |
| description |
A fragment of the NWA 2975 Martian meteorite, an enriched basaltic shergottite, was analysed to complete its geochemical characterisation performed 10 years ago. By this means, the feasibility of the employed techniques in a combined way for present and future space exploration missions can be tested. For this aim, Raman spectroscopy was used supported by micro energy dispersive X-ray fluorescence (μ-EDXRF) and laser-induced breakdown spectroscopy (LIBS) for an accurate interpretation of molecular and elemental results. Raman spectroscopy results from two setups, InVia from Renishaw and RLS Simulator, were compared. The major minerals detected by Raman spectroscopy were pyroxenes (mainly augite, pigeonite and enstatite) and plagioclases (mainly shocked maskelynite). Raman spectroscopy allowed defining different metal compositions for these main minerals based on the secondary Raman spectroscopy bands in the 200–500 cm−1 region. In addition, other minerals were found such as merrillite, as well as pyrrhotite and apatite, in several veins and cracks of the meteorite, in agreement with the initial report by the Meteoritical Bulletin. Moreover, it should be highlighted that coesite was found for the very first time in this meteorite. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2023-01-01 2023 2023-01-01 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 VoR http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/20.500.14352/92373 |
| url |
https://hdl.handle.net/20.500.14352/92373 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
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application/pdf |
| dc.publisher.none.fl_str_mv |
Wiley |
| publisher.none.fl_str_mv |
Wiley |
| dc.source.none.fl_str_mv |
reponame:Docta Complutense instname:Universidad Complutense de Madrid (UCM) |
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Universidad Complutense de Madrid (UCM) |
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Docta Complutense |
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Docta Complutense |
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15,301603 |