Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites
We describe a simple and scalable method for incorporating thermoplastic agents into fiber reinforced polymers (FRPs). Poly(ethylene-co-methacrylic acid) (EMAA) nanoparticles were successfully deposited on the surface of carbon fibers via spray coating. EMAA was finely distributed and exhibited stro...
| Autores: | , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/330621 |
| Acceso en línea: | http://hdl.handle.net/10261/330621 |
| Access Level: | acceso abierto |
| Palabra clave: | Self-healing Thermoset Thermoplastic Coating FRPs |
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Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing compositesPeñas-Caballero, MónicaChemello, EnricoGrande, Antonio M.Hernández, MarianellaVerdejo, RaquelLópez-Manchado, Miguel A.Self-healing Thermoset Thermoplastic Coating FRPsWe describe a simple and scalable method for incorporating thermoplastic agents into fiber reinforced polymers (FRPs). Poly(ethylene-co-methacrylic acid) (EMAA) nanoparticles were successfully deposited on the surface of carbon fibers via spray coating. EMAA was finely distributed and exhibited strong adhesion to the fibers. The EMAA-coated carbon fibers improved the fracture toughness and provided the FRPs with self-healing ability. The resulting healing efficiency, based on the recovery of the interlaminar fracture toughness, was above 40 % and gradually decreased after three repair cycles. The repair mechanism of the system involves the inherent flow capacity of the thermoplastic and formation of interfacial bridging between the two damaged interphases. This methodology allows pure resin to be used without any chemical modification or adverse effects on its viscosity, and the coated fiber can be stored until use.This research was funded by the Spanish Research Agency, grant numbers PID2019-107501RB-I00/AEI/10.13039/501100011033 and RYC-2017-22837. Monica ´ Penas-Caballero ˜ thanks a Predoctoral contract (BES-2017-079899Peer reviewedElsevierAgencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2023202320232023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/330621reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107501RB-I00http://dx.doi.org/10.1016/j.compositesa.2023.107537Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3306212026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| title |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| spellingShingle |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites Peñas-Caballero, Mónica Self-healing Thermoset Thermoplastic Coating FRPs |
| title_short |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| title_full |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| title_fullStr |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| title_full_unstemmed |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| title_sort |
Poly(ethylene-co-methacrylic acid) coated carbon fiber for self-healing composites |
| dc.creator.none.fl_str_mv |
Peñas-Caballero, Mónica Chemello, Enrico Grande, Antonio M. Hernández, Marianella Verdejo, Raquel López-Manchado, Miguel A. |
| author |
Peñas-Caballero, Mónica |
| author_facet |
Peñas-Caballero, Mónica Chemello, Enrico Grande, Antonio M. Hernández, Marianella Verdejo, Raquel López-Manchado, Miguel A. |
| author_role |
author |
| author2 |
Chemello, Enrico Grande, Antonio M. Hernández, Marianella Verdejo, Raquel López-Manchado, Miguel A. |
| author2_role |
author author author author author |
| dc.contributor.none.fl_str_mv |
Agencia Estatal de Investigación (España) Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Self-healing Thermoset Thermoplastic Coating FRPs |
| topic |
Self-healing Thermoset Thermoplastic Coating FRPs |
| description |
We describe a simple and scalable method for incorporating thermoplastic agents into fiber reinforced polymers (FRPs). Poly(ethylene-co-methacrylic acid) (EMAA) nanoparticles were successfully deposited on the surface of carbon fibers via spray coating. EMAA was finely distributed and exhibited strong adhesion to the fibers. The EMAA-coated carbon fibers improved the fracture toughness and provided the FRPs with self-healing ability. The resulting healing efficiency, based on the recovery of the interlaminar fracture toughness, was above 40 % and gradually decreased after three repair cycles. The repair mechanism of the system involves the inherent flow capacity of the thermoplastic and formation of interfacial bridging between the two damaged interphases. This methodology allows pure resin to be used without any chemical modification or adverse effects on its viscosity, and the coated fiber can be stored until use. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2023 2023 2023 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
| format |
article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/330621 |
| url |
http://hdl.handle.net/10261/330621 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107501RB-I00 http://dx.doi.org/10.1016/j.compositesa.2023.107537 Sí |
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info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869415424648544256 |
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15,812429 |