V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells

Over the last few years, transition metal oxide layers have been proposed as selective contacts both for electrons and holes and successfully applied to silicon solar cells. However, better published results need the use of both a thin and high quality intrinsic amorphous Si layer and TCO (Transpare...

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Autores: Masmitjà Rusiñol, Gerard|||0000-0001-9541-7586, Gerling Sarabia, Luis Guillermo, Ortega Villasclaras, Pablo Rafael|||0000-0001-6577-614X, Puigdollers i González, Joaquim|||0000-0002-1834-2565, Martín García, Isidro|||0000-0001-8833-9057, Voz Sánchez, Cristóbal|||0000-0002-0320-9606, Alcubilla González, Ramón|||0000-0003-4827-4513
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/116632
Acceso en línea:https://hdl.handle.net/2117/116632
https://dx.doi.org/10.1039/C7TA01959A
Access Level:acceso abierto
Palabra clave:Solar cells
Bateries solars
Cèl·lules solars
Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica::Cèl·lules solars
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spelling V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cellsMasmitjà Rusiñol, Gerard|||0000-0001-9541-7586Gerling Sarabia, Luis GuillermoOrtega Villasclaras, Pablo Rafael|||0000-0001-6577-614XPuigdollers i González, Joaquim|||0000-0002-1834-2565Martín García, Isidro|||0000-0001-8833-9057Voz Sánchez, Cristóbal|||0000-0002-0320-9606Alcubilla González, Ramón|||0000-0003-4827-4513Solar cellsBateries solarsCèl·lules solarsÀrees temàtiques de la UPC::Energies::Energia solar fotovoltaica::Cèl·lules solarsOver the last few years, transition metal oxide layers have been proposed as selective contacts both for electrons and holes and successfully applied to silicon solar cells. However, better published results need the use of both a thin and high quality intrinsic amorphous Si layer and TCO (Transparent Conductive Oxide) films. In this work, we explore the use of vanadium suboxide (V2Ox) capped with a thin Ni layer as a hole transport layer trying to avoid both the intrinsic amorphous silicon layer and the TCO contact layer. Obtained figures of merit for Ni/V2Ox/c-Si(n) test samples are saturation current densities of 175 fA cm-2 and specific contact resistance below 115 mO cm2 on 40 nm thick V2Ox layers. Finally, the Ni/V2Ox stack is used with an interdigitated back-contacted c-Si(n) solar cell architecture fully fabricated at low temperatures. An open circuit voltage, a short circuit current and a fill factor of 656 mV, 40.7 mA cm-2 and 74.0% are achieved, respectively, leading to a power conversion efficiency of 19.7%. These results confirm the high potential of Ni/V2Ox stacks as hole-selective contacts on crystalline silicon photovoltaics.Royal Society of Chemistry20172017-04-0620182018-04-24journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/2117/116632https://dx.doi.org/10.1039/C7TA01959Areponame:UPCommons. Portal del coneixement obert de la UPCinstname:Universitat Politècnica de Catalunya (UPC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:upcommons.upc.edu:2117/1166322026-05-27T15:37:01Z
dc.title.none.fl_str_mv V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
title V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
spellingShingle V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
Masmitjà Rusiñol, Gerard|||0000-0001-9541-7586
Solar cells
Bateries solars
Cèl·lules solars
Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica::Cèl·lules solars
title_short V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
title_full V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
title_fullStr V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
title_full_unstemmed V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
title_sort V2Ox-based hole-selective contacts for c-Si interdigitated back-contacted solar cells
dc.creator.none.fl_str_mv Masmitjà Rusiñol, Gerard|||0000-0001-9541-7586
Gerling Sarabia, Luis Guillermo
Ortega Villasclaras, Pablo Rafael|||0000-0001-6577-614X
Puigdollers i González, Joaquim|||0000-0002-1834-2565
Martín García, Isidro|||0000-0001-8833-9057
Voz Sánchez, Cristóbal|||0000-0002-0320-9606
Alcubilla González, Ramón|||0000-0003-4827-4513
author Masmitjà Rusiñol, Gerard|||0000-0001-9541-7586
author_facet Masmitjà Rusiñol, Gerard|||0000-0001-9541-7586
Gerling Sarabia, Luis Guillermo
Ortega Villasclaras, Pablo Rafael|||0000-0001-6577-614X
Puigdollers i González, Joaquim|||0000-0002-1834-2565
Martín García, Isidro|||0000-0001-8833-9057
Voz Sánchez, Cristóbal|||0000-0002-0320-9606
Alcubilla González, Ramón|||0000-0003-4827-4513
author_role author
author2 Gerling Sarabia, Luis Guillermo
Ortega Villasclaras, Pablo Rafael|||0000-0001-6577-614X
Puigdollers i González, Joaquim|||0000-0002-1834-2565
Martín García, Isidro|||0000-0001-8833-9057
Voz Sánchez, Cristóbal|||0000-0002-0320-9606
Alcubilla González, Ramón|||0000-0003-4827-4513
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Solar cells
Bateries solars
Cèl·lules solars
Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica::Cèl·lules solars
topic Solar cells
Bateries solars
Cèl·lules solars
Àrees temàtiques de la UPC::Energies::Energia solar fotovoltaica::Cèl·lules solars
description Over the last few years, transition metal oxide layers have been proposed as selective contacts both for electrons and holes and successfully applied to silicon solar cells. However, better published results need the use of both a thin and high quality intrinsic amorphous Si layer and TCO (Transparent Conductive Oxide) films. In this work, we explore the use of vanadium suboxide (V2Ox) capped with a thin Ni layer as a hole transport layer trying to avoid both the intrinsic amorphous silicon layer and the TCO contact layer. Obtained figures of merit for Ni/V2Ox/c-Si(n) test samples are saturation current densities of 175 fA cm-2 and specific contact resistance below 115 mO cm2 on 40 nm thick V2Ox layers. Finally, the Ni/V2Ox stack is used with an interdigitated back-contacted c-Si(n) solar cell architecture fully fabricated at low temperatures. An open circuit voltage, a short circuit current and a fill factor of 656 mV, 40.7 mA cm-2 and 74.0% are achieved, respectively, leading to a power conversion efficiency of 19.7%. These results confirm the high potential of Ni/V2Ox stacks as hole-selective contacts on crystalline silicon photovoltaics.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-04-06
2018
2018-04-24
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/2117/116632
https://dx.doi.org/10.1039/C7TA01959A
url https://hdl.handle.net/2117/116632
https://dx.doi.org/10.1039/C7TA01959A
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:UPCommons. Portal del coneixement obert de la UPC
instname:Universitat Politècnica de Catalunya (UPC)
instname_str Universitat Politècnica de Catalunya (UPC)
reponame_str UPCommons. Portal del coneixement obert de la UPC
collection UPCommons. Portal del coneixement obert de la UPC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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