Building Zeolites from Precrystallized Units: Nanoscale Architecture

Since the early reports by Barrer in the 1940s on converting natural minerals into synthetic zeolites, the use of precrystallized zeolites as crucial inorganic directing agents to synthesize other crystalline zeolites with improved physicochemical properties has become a very important research fiel...

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Detalhes bibliográficos
Autores: Li, Chengeng, Moliner Marín, Manuel, Corma, Avelino
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/202584
Acesso em linha:http://hdl.handle.net/10261/202584
Access Level:acceso abierto
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spelling Building Zeolites from Precrystallized Units: Nanoscale ArchitectureLi, ChengengMoliner Marín, ManuelCorma, AvelinoSince the early reports by Barrer in the 1940s on converting natural minerals into synthetic zeolites, the use of precrystallized zeolites as crucial inorganic directing agents to synthesize other crystalline zeolites with improved physicochemical properties has become a very important research field, allowing the design, particularly in recent years, of new industrial catalysts. This Review highlights how the presence of some crystalline fragments in the synthesis media, such as small secondary building units (SBUs) or layered substructures, not only favors the crystallization of other zeolites with similar SBUs or layers, but also permits control over important parameters affecting their catalytic activity (chemical composition, crystal size, or porosity, etc.). Recent advances in the preparation of 3D and 2D zeolites through seeding and zeolite-to-zeolite transformation processes will be discussed extensively in this Review, including their preparation in the presence or absence of organic structure-directing agents (OSDAs). The aim is to introduce general guidelines for more efficient approaches for target zeolites.This work has been supported by the Spanish Government (MINECO through “Severo Ochoa” (SEV‐2016‐0683) and MAT2015‐71261‐R), by the European Union through ERC‐AdG‐2014‐671093 (SynCatMatch), and by the Fundación Ramón Areces (through the “Life and Materials Science” program).John Wiley & SonsEuropean CommissionEuropean Research CouncilMinisterio de Economía y Competitividad (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2020202020182020info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/202584reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/671093info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2016-0683info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-71261-Rhttp://dx.doi.org/10.1002/anie.201711422Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2025842026-05-22T06:33:51Z
dc.title.none.fl_str_mv Building Zeolites from Precrystallized Units: Nanoscale Architecture
title Building Zeolites from Precrystallized Units: Nanoscale Architecture
spellingShingle Building Zeolites from Precrystallized Units: Nanoscale Architecture
Li, Chengeng
title_short Building Zeolites from Precrystallized Units: Nanoscale Architecture
title_full Building Zeolites from Precrystallized Units: Nanoscale Architecture
title_fullStr Building Zeolites from Precrystallized Units: Nanoscale Architecture
title_full_unstemmed Building Zeolites from Precrystallized Units: Nanoscale Architecture
title_sort Building Zeolites from Precrystallized Units: Nanoscale Architecture
dc.creator.none.fl_str_mv Li, Chengeng
Moliner Marín, Manuel
Corma, Avelino
author Li, Chengeng
author_facet Li, Chengeng
Moliner Marín, Manuel
Corma, Avelino
author_role author
author2 Moliner Marín, Manuel
Corma, Avelino
author2_role author
author
dc.contributor.none.fl_str_mv European Commission
European Research Council
Ministerio de Economía y Competitividad (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description Since the early reports by Barrer in the 1940s on converting natural minerals into synthetic zeolites, the use of precrystallized zeolites as crucial inorganic directing agents to synthesize other crystalline zeolites with improved physicochemical properties has become a very important research field, allowing the design, particularly in recent years, of new industrial catalysts. This Review highlights how the presence of some crystalline fragments in the synthesis media, such as small secondary building units (SBUs) or layered substructures, not only favors the crystallization of other zeolites with similar SBUs or layers, but also permits control over important parameters affecting their catalytic activity (chemical composition, crystal size, or porosity, etc.). Recent advances in the preparation of 3D and 2D zeolites through seeding and zeolite-to-zeolite transformation processes will be discussed extensively in this Review, including their preparation in the presence or absence of organic structure-directing agents (OSDAs). The aim is to introduce general guidelines for more efficient approaches for target zeolites.
publishDate 2018
dc.date.none.fl_str_mv 2018
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
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info:eu-repo/semantics/acceptedVersion
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status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/202584
url http://hdl.handle.net/10261/202584
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
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info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2016-0683
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-71261-R
http://dx.doi.org/10.1002/anie.201711422
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv John Wiley & Sons
publisher.none.fl_str_mv John Wiley & Sons
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
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