Phase-diagrams of simple fluids with extreme pair potentials

It is shown that strongly reducing the range of the attractions of a simple fluid will transform its phase diagram from the usual type, with a fluid-fluid critical point and a fluid-fluid-solid triple point, into its fluid-solid mirror image, with a solid-solid critical point and a solid-solid-fluid...

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Detalles Bibliográficos
Autores: Fernández Tejero, Carlos, Daanoun, A., Lekkerkerker, H. N. W., Baus, M.
Tipo de recurso: artículo
Fecha de publicación:1994
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/58886
Acceso en línea:https://hdl.handle.net/20.500.14352/58886
Access Level:acceso abierto
Palabra clave:536
Polymer
Termodinámica
2213 Termodinámica
Descripción
Sumario:It is shown that strongly reducing the range of the attractions of a simple fluid will transform its phase diagram from the usual type, with a fluid-fluid critical point and a fluid-fluid-solid triple point, into its fluid-solid mirror image, with a solid-solid critical point and a solid-solid-fluid triple point. This scenario could be of relevance to the phase behavior of colloidal dispersions.