Dry Reforming of Methane on a Highly-Active Ni-CeO2Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking

Ni-CeO2is a highly efficient, stable and non-expensive catalyst for methane dry reforming at relative low temperatures (700 K). The active phase of the catalyst consists of small nanoparticles of nickel dispersed on partially reduced ceria. Experiments of ambient pressure XPS indicate that methane d...

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Detalhes bibliográficos
Autores: Liu, Z., Grinter, D.C., Lustemberg, Pablo G., Nguyen-Phan, T.-D., Zhou, Y., Luo, S., Waluyo, I., Crumlin, E.J., Stacchiola, D.J., Zhou, J., Carrasco, J., Busnengo, H.F., Ganduglia-Pirovano, M. V., Senanayake, S.D., Rodriguez, J.A.
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2016
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/376518
Acesso em linha:http://hdl.handle.net/10261/376518
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84992311171&doi=10.1002%2fanie.201602489&partnerID=40&md5=a10323b963c8c38bc9378ecbe7885262
Access Level:Acceso aberto
Palavra-chave:ceria
density functional theory
methane dissociation
nickel
X-ray photoelectron spectroscopy
Descrição
Resumo:Ni-CeO2is a highly efficient, stable and non-expensive catalyst for methane dry reforming at relative low temperatures (700 K). The active phase of the catalyst consists of small nanoparticles of nickel dispersed on partially reduced ceria. Experiments of ambient pressure XPS indicate that methane dissociates on Ni/CeO2at temperatures as low as 300 K, generating CHxand COxspecies on the surface of the catalyst. Strong metal–support interactions activate Ni for the dissociation of methane. The results of density-functional calculations show a drop in the effective barrier for methane activation from 0.9 eV on Ni(111) to only 0.15 eV on Ni/CeO2−x(111). At 700 K, under methane dry reforming conditions, no signals for adsorbed CHxor C species are detected in the C 1s XPS region. The reforming of methane proceeds in a clean and efficient way. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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