A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(I...

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Detalles Bibliográficos
Autores: Hidalgo, Nereida, Cruz-Martínez, Felipe de la, Martín, M. Trinidad, Nicasio, M. Carmen, Campos, Jesús
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/282177
Acceso en línea:http://hdl.handle.net/10261/282177
Access Level:acceso abierto
Descripción
Sumario:A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(II) structure.

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