Not dark yet for strong light-matter coupling to accelerate singlet fission dynamics
Polaritons are unique hybrid light-matter states that offer an alternative way to manipulate chemical processes. In this work, we show that singlet fission dynamics can be accelerated under strong light-matter coupling. For superexchange-mediated singlet fission, state mixing speeds up the dynamics...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/705832 |
| Acceso en línea: | http://hdl.handle.net/10486/705832 https://dx.doi.org/10.1016/j.xcrp.2022.100841 |
| Access Level: | acceso abierto |
| Palabra clave: | Polaritons Plasmon Excitons Física |
| Sumario: | Polaritons are unique hybrid light-matter states that offer an alternative way to manipulate chemical processes. In this work, we show that singlet fission dynamics can be accelerated under strong light-matter coupling. For superexchange-mediated singlet fission, state mixing speeds up the dynamics in cavities when the lower polariton is close in energy to the multiexcitonic state. This effect is more pronounced in non-conventional singlet fission materials in which the energy gap between the bright singlet exciton and the multiexcitonic state is large (>0.1 eV). In this case, the dynamics is dominated by the polaritonic modes and not by the bare-molecule-like dark states, and, additionally, the resonant enhancement due to strong coupling is robust even for energetically broad molecular states. The present results provide a new strategy to expand the range of suitable materials for efficient singlet fission by making use of strong light-matter coupling |
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