The relation between the rheological properties of gels and the mechanical properties of their corresponding aerogels

A series of low density, highly porous clay/poly(vinyl alcohol) composite aerogels, incorporating ammonium alginate, were fabricated via a convenient and eco-friendly freeze drying method. It is significant to understand rheological properties of precursor gels because they directly affect the form...

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Detalhes bibliográficos
Autores: Sun, Mingze, Sun, Hua, Wang, Yutao, Sánchez Soto, Miguel|||0000-0002-0023-5059, Schiraldi, David A.
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/118178
Acesso em linha:https://hdl.handle.net/2117/118178
https://dx.doi.org/10.3390/gels4020033
Access Level:acceso abierto
Palavra-chave:Aerogels
Rheology
Materials--Mechanical properties
Aerogel
Mechanical properties
Reologia
Materials -- Propietats mecàniques
Àrees temàtiques de la UPC::Enginyeria dels materials
Àrees temàtiques de la UPC::Enginyeria dels materials::Materials compostos
Descrição
Resumo:A series of low density, highly porous clay/poly(vinyl alcohol) composite aerogels, incorporating ammonium alginate, were fabricated via a convenient and eco-friendly freeze drying method. It is significant to understand rheological properties of precursor gels because they directly affect the form of aerogels and their processing behaviors. The introduction of ammonium alginate impacted the rheological properties of colloidal gels and improved the mechanical performance of the subject aerogels. The specific compositions and processing conditions applied to those colloidal gel systems brought about different aerogel morphologies, which in turn translated into the observed mechanical properties. The bridge between gel rheologies and aerogel structures are established in the present work