Synthesis of the BCDE Molecular Fragment of Azadiradione Mediated by Titanocene(III)
[EN]A practical, short, and diastereoselective synthesis of the azadiradione BCDE fragment from a readily available starting material is described. The key step was the titanocene(III)-promoted tandem cyclization of unsaturated epoxy nitrile.
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2013 |
| País: | España |
| Institución: | Universidad de Salamanca (USAL) |
| Repositorio: | GREDOS. Repositorio Institucional de la Universidad de Salamanca |
| OAI Identifier: | oai:gredos.usal.es:10366/154245 |
| Acceso en línea: | http://hdl.handle.net/10366/154245 |
| Access Level: | acceso abierto |
| Palabra clave: | Anions Cyclization Hydrocarbons Nitrogen compounds Organic polymers 2306 Química Orgánica |
| Sumario: | [EN]A practical, short, and diastereoselective synthesis of the azadiradione BCDE fragment from a readily available starting material is described. The key step was the titanocene(III)-promoted tandem cyclization of unsaturated epoxy nitrile. |
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