Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution
Replacing conventional plastics with other products obtained from biobased and biodegradable raw materials is an increasingly studied solution. In this line, the development of protein-based bioplastics is a promising alternative. However, for some applications, such as packaging it would be necessa...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universidad de Huelva (UHU) |
| Repositorio: | Arias Montano. Repositorio Institucional de la Universidad de Huelva |
| Idioma: | inglés |
| OAI Identifier: | oai:ariasmontano.uhu.es:10272/23264 |
| Acceso en línea: | https://hdl.handle.net/10272/23264 |
| Access Level: | acceso abierto |
| Palabra clave: | Pea protein Bioplastics Injection moulding Genipin Chemical crosslinking 23 Química |
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Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking EvolutionPérez Puyana, VíctorCortés Triviño, EsperanzaJiménez Rosado, MercedesRomero, A.Martinez García, InmaculadaPea proteinBioplasticsInjection mouldingGenipinChemical crosslinking23 QuímicaReplacing conventional plastics with other products obtained from biobased and biodegradable raw materials is an increasingly studied solution. In this line, the development of protein-based bioplastics is a promising alternative. However, for some applications, such as packaging it would be necessary to improve their properties by including an additional stage to crosslink the protein chains during the production of bioplastics. Therefore, pea protein-based bioplastics crosslinked with genipin, a natural non-toxic chemical crosslinking agent, are evaluated in this study. The bioplastics are obtained via injection moulding and genipin, is included in the initial formulation. Specifcally, the concentration of genipin and the efects on the protein blends with genipin over days are evaluated. The evolution of the reaction is followed by the colour change of the blend, together with thermal analyses and infrared spectroscopy. Results showed the evolution of the crosslinking in the blends resulted in conformational changes that resulted in the modifcation of the initial yellowish colour to a blueish system. Respect their bioplastics, more deformable systems with a lower water absorption capability are obtained by using genipin as crosslinking agentSpringer20232023-07-0120232023-07-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10272/23264reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelvainstname:Universidad de Huelva (UHU)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:ariasmontano.uhu.es:10272/232642026-06-02T14:58:11Z |
| dc.title.none.fl_str_mv |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| title |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| spellingShingle |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution Pérez Puyana, Víctor Pea protein Bioplastics Injection moulding Genipin Chemical crosslinking 23 Química |
| title_short |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| title_full |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| title_fullStr |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| title_full_unstemmed |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| title_sort |
Pea Protein‑Based Bioplastics Crosslinked with Genipin: Analysis of the Crosslinking Evolution |
| dc.creator.none.fl_str_mv |
Pérez Puyana, Víctor Cortés Triviño, Esperanza Jiménez Rosado, Mercedes Romero, A. Martinez García, Inmaculada |
| author |
Pérez Puyana, Víctor |
| author_facet |
Pérez Puyana, Víctor Cortés Triviño, Esperanza Jiménez Rosado, Mercedes Romero, A. Martinez García, Inmaculada |
| author_role |
author |
| author2 |
Cortés Triviño, Esperanza Jiménez Rosado, Mercedes Romero, A. Martinez García, Inmaculada |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
|
| dc.subject.none.fl_str_mv |
Pea protein Bioplastics Injection moulding Genipin Chemical crosslinking 23 Química |
| topic |
Pea protein Bioplastics Injection moulding Genipin Chemical crosslinking 23 Química |
| description |
Replacing conventional plastics with other products obtained from biobased and biodegradable raw materials is an increasingly studied solution. In this line, the development of protein-based bioplastics is a promising alternative. However, for some applications, such as packaging it would be necessary to improve their properties by including an additional stage to crosslink the protein chains during the production of bioplastics. Therefore, pea protein-based bioplastics crosslinked with genipin, a natural non-toxic chemical crosslinking agent, are evaluated in this study. The bioplastics are obtained via injection moulding and genipin, is included in the initial formulation. Specifcally, the concentration of genipin and the efects on the protein blends with genipin over days are evaluated. The evolution of the reaction is followed by the colour change of the blend, together with thermal analyses and infrared spectroscopy. Results showed the evolution of the crosslinking in the blends resulted in conformational changes that resulted in the modifcation of the initial yellowish colour to a blueish system. Respect their bioplastics, more deformable systems with a lower water absorption capability are obtained by using genipin as crosslinking agent |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2023-07-01 2023 2023-07-01 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 VoR http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://hdl.handle.net/10272/23264 |
| url |
https://hdl.handle.net/10272/23264 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Atribución-NoComercial-SinDerivadas 3.0 España http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Atribución-NoComercial-SinDerivadas 3.0 España http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Springer |
| publisher.none.fl_str_mv |
Springer |
| dc.source.none.fl_str_mv |
reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelva instname:Universidad de Huelva (UHU) |
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Universidad de Huelva (UHU) |
| reponame_str |
Arias Montano. Repositorio Institucional de la Universidad de Huelva |
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Arias Montano. Repositorio Institucional de la Universidad de Huelva |
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15,81155 |