Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst

Catalysis is a powerful tool for the synthesis of a wide variety of compounds, it allows to increase the rate in which a chemical reaction reaches the equilibrium without being consumed in the process. However, for the synthesis of more complex compounds usually homogeneous catalysis is needed. Nowa...

ver descrição completa

Detalhes bibliográficos
Autor: Fariña Torres, Víctor
Formato: tesis doctoral
Fecha de publicación:2025
País:España
Recursos:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/42114
Acesso em linha:https://hdl.handle.net/10347/42114
Access Level:acceso abierto
Palavra-chave:Heterogeneous
recyclable
palladium-catalysis
heterobimetallic
MOF
221001 Catálisis
id ES_9f254c5e96e2ccadefc6be6c16d0bd7d
oai_identifier_str oai:minerva.usc.gal:10347/42114
network_acronym_str ES
network_name_str España
repository_id_str
spelling Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalystFariña Torres, VíctorHeterogeneousrecyclablepalladium-catalysisheterobimetallicMOF221001 CatálisisCatalysis is a powerful tool for the synthesis of a wide variety of compounds, it allows to increase the rate in which a chemical reaction reaches the equilibrium without being consumed in the process. However, for the synthesis of more complex compounds usually homogeneous catalysis is needed. Nowadays the research of new heterogeneous catalysts that have both the advantages of heterogeneous and homogeneous catalysts has greatly increased. On this field metal-organic frameworks have emerged as powerful catalyst that fulfill both the complexity of the homogeneous catalysts and the easy recyclability and robustness of the heterogeneous catalysts. This thesis presents the principal results obtained in the investigation of the applications of a novel bimetallic framework with iron clusters and a palladium metalloligand in different palladium catalyzed reactions. We focused in the carbon-carbon formation reactions.Fañanás-Mastral, MartínUniversidade de Santiago de Compostela. Escola de Doutoramento Internacional (EDIUS)20252025-01-0120252025-01-01doctoral thesishttp://purl.org/coar/resource_type/c_db06info:eu-repo/semantics/doctoralThesisapplication/pdfhttps://hdl.handle.net/10347/42114reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/421142026-06-15T12:47:27Z
dc.title.none.fl_str_mv Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
title Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
spellingShingle Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
Fariña Torres, Víctor
Heterogeneous
recyclable
palladium-catalysis
heterobimetallic
MOF
221001 Catálisis
title_short Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
title_full Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
title_fullStr Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
title_full_unstemmed Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
title_sort Development of carbon-carbon bond forming reactions using a heterobimetallic Pd-Fe metal-organic framework as heterogenous catalyst
dc.creator.none.fl_str_mv Fariña Torres, Víctor
author Fariña Torres, Víctor
author_facet Fariña Torres, Víctor
author_role author
dc.contributor.none.fl_str_mv Fañanás-Mastral, Martín
Universidade de Santiago de Compostela. Escola de Doutoramento Internacional (EDIUS)
dc.subject.none.fl_str_mv Heterogeneous
recyclable
palladium-catalysis
heterobimetallic
MOF
221001 Catálisis
topic Heterogeneous
recyclable
palladium-catalysis
heterobimetallic
MOF
221001 Catálisis
description Catalysis is a powerful tool for the synthesis of a wide variety of compounds, it allows to increase the rate in which a chemical reaction reaches the equilibrium without being consumed in the process. However, for the synthesis of more complex compounds usually homogeneous catalysis is needed. Nowadays the research of new heterogeneous catalysts that have both the advantages of heterogeneous and homogeneous catalysts has greatly increased. On this field metal-organic frameworks have emerged as powerful catalyst that fulfill both the complexity of the homogeneous catalysts and the easy recyclability and robustness of the heterogeneous catalysts. This thesis presents the principal results obtained in the investigation of the applications of a novel bimetallic framework with iron clusters and a palladium metalloligand in different palladium catalyzed reactions. We focused in the carbon-carbon formation reactions.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025-01-01
2025
2025-01-01
dc.type.none.fl_str_mv doctoral thesis
http://purl.org/coar/resource_type/c_db06
dc.type.openaire.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
dc.identifier.none.fl_str_mv https://hdl.handle.net/10347/42114
url https://hdl.handle.net/10347/42114
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869414903388831744
score 15,811543

Registos relacionados